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Crystal structure of (1E,1'E)-1,1'-(pyridine-2,6-di-yl)bis-[N-(2,3,4,5,6-penta-fluoro-phen-yl)ethan-1-imine].

ABSTRACT: The title compound, C₂₁H₉F₁₀N₃, represents a potential redox non-innocent pyridine di-imine ligand system. It consists of a central pyridine ring with two penta-fluoro-phenyl substituted imine groups in positions 2 and 6. The whole mol-ecule is generated by mirror symmetry, the mirror bis-ecting the N and para-C atom of the pyridine ring. The perfluoro-phenyl ring is inclined to the pyridine ring by 73.67?(8)°. In the crystal, mol-ecules stack along the a axis, but there are no significant inter-molecular inter-actions present.

SUBMITTER: Boyle J

PROVIDER: S-EPMC5499267 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature

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Crystal structure of (1E,1'E)-1,1'-(pyridine-2,6-di-yl)bis-[N-(2,3,4,5,6-penta-fluoro-phen-yl)ethan-1-imine].

Boyle Jenna J Breakfield Catherine C Buck Leah L McMahon Catherine C Babbini Dominic C DC

Acta crystallographica. Section E, Crystallographic communications 20170602 Pt 7

The title compound, C21H9F10N3, represents a potential redox non-innocent pyridine di-imine ligand system. It consists of a central pyridine ring with two penta-fluoro-phenyl substituted imine groups in positions 2 and 6. The whole mol-ecule is generated by mirror symmetry, the mirror bis-ecting the N and para-C atom of the pyridine ring. The perfluoro-phenyl ring is inclined to the pyridine ring by 73.67 (8)°. In the crystal, mol-ecules stack a ...[more]

PMID: 28775859

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