Crystal structure of di-chlorido-(1,2-phenyl-enedi-amine-κ²N,N')platinum(II).

ABSTRACT: The Pt^II atom in the title compound, [PtCl₂{(C₆H₄)(NH₂)₂}], lies on a twofold rotation axis and has a slightly distorted square-planar coordination environment defined by two N atoms of an 1,2-phenyl-enedi-amine ligand and two Cl^- ions. In the crystal, the planar complex mol-ecules are stacked parallel to the c axis, resulting in a columnar structure. In a column, an infinite almost straight Pt⋯Pt chain is formed, suggesting weak metal-metal inter-actions [Pt⋯Pt = 3.3475 (8) Å]. The crystal packing is stabilized by a three-dimensional N-H⋯Cl hydrogen-bonding network between the amino groups and the Cl ligands of adjacent mol-ecules.

SUBMITTER: Konno Y 

PROVIDER: S-EPMC5499279 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature