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Poly[bis-(?2-1,3-phenyl-enedi-amine-?(2) N:N')di-?-thio-cyanato-?(2) N:S;?(2) S:N-cadmium].

ABSTRACT: The structure of the title polymeric compound, [Cd(SCN)2(C6H8N2)2] n , exhibits a two-dimensional staircase-like structure parallel to (010) in which the Cd(II) atom lies on a twofold rotation axis and has a distorted octa-hedral CdS2N4 geometry involving four ?-1,3-(SCN) group donors and two N-atom donors from 1,3-phenyl-enedi-amine ligands, which also have twofold symmetry. The major contributions to the cohesion and the stability of this two-dimensional polymeric structure are the covalent Cd-S,N bonds and one weak intra-layer N-H?S hydrogen bond.

SUBMITTER: Chemli R

PROVIDER: S-EPMC3885002 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature

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Poly[bis-(μ2-1,3-phenyl-enedi-amine-κ(2) N:N')di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N-cadmium].

Chemli Rakia R Kamoun Slaheddine S Roisnel Thierry T

Acta crystallographica. Section E, Structure reports online 20131120 Pt 12

The structure of the title polymeric compound, [Cd(SCN)2(C6H8N2)2] n , exhibits a two-dimensional staircase-like structure parallel to (010) in which the Cd(II) atom lies on a twofold rotation axis and has a distorted octa-hedral CdS2N4 geometry involving four μ-1,3-(SCN) group donors and two N-atom donors from 1,3-phenyl-enedi-amine ligands, which also have twofold symmetry. The major contributions to the cohesion and the stability of this two-dimensional polymeric structure are the covalent Cd ...[more]

PMID: 24454177

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Project description:In the crystal structure of the title compound, {(C(12)H(14)N(2))[Fe(NCS)(4)]}(n), the iron(II) cation is coordinated by four N-bonded and two S-bonded thio-cyanate anions in a distorted octa-hedral coordination mode. The asymmetric unit consists of half an iron(II) cation and half a protonated (E)-4,4'-(ethane-1,2-di-yl)dipyridinium dication, each located on a centre of inversion. In addition, there are two thio-cyanate anions in general positions. The crystal structure consists of Fe-(NCS)(2)-Fe chains in which each iron(II) cation is additionally coordinated by two terminal N-bonded thio-cyanate anions. Non-coordinating dipyridinium dications are present between the thiocyanatoferrate(II) chains and are connected to the anions via N-H⋯N and N-H⋯S hydrogen-bond interactions.

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