Ontology highlight
ABSTRACT:
SUBMITTER: Becker P
PROVIDER: S-EPMC5499658 | biostudies-literature | 2017 Jun
REPOSITORIES: biostudies-literature
Becker Peter P Duhamel Thomas T Stein Christopher J CJ Reiher Markus M Muñiz Kilian K
Angewandte Chemie (International ed. in English) 20170601 27
An unprecedented method that makes use of the cooperative interplay between molecular iodine and photoredox catalysis has been developed for dual light-activated intramolecular benzylic C-H amination. Iodine serves as the catalyst for the formation of a new C-N bond by activating a remote Csp3 -H bond (1,5-HAT process) under visible-light irradiation while the organic photoredox catalyst TPT effects the reoxidation of the molecular iodine catalyst. To explain the compatibility of the two involve ...[more]