Ontology highlight
ABSTRACT:
SUBMITTER: Waeles P
PROVIDER: S-EPMC5502395 | biostudies-literature | 2015 Aug
REPOSITORIES: biostudies-literature
Chemical science 20150602 8
We report a diverted route to [1]rotaxane and tris-branched [1]rotaxane that are devoid of any efficient template and which could not be obtained by classical straightforward strategies. The described chemical route relies on the utilization of a "macrocycle transporter", which is able first to bind a macrocycle, second to link temporarily a triazolium-containing molecular axle, and third to deliver the macrocycle around the new docked axle through molecular machinery in a [1]rotaxane structure. ...[more]