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A FISCHER INDOLIZATION STRATEGY TOWARD THE TOTAL SYNTHESIS OF (-)-GONIOMITINE.

ABSTRACT: A Fischer indolization strategy toward the core of (-)-goniomitine is reported. Initial investigations into the Pd-catalyzed asymmetric allylic alkylation of dihydropyrido[1,2-a]indolone (DHPI) substrates are also discussed.

SUBMITTER: Pritchett BP

PROVIDER: S-EPMC5502790 | biostudies-literature | 2017

REPOSITORIES: biostudies-literature

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A FISCHER INDOLIZATION STRATEGY TOWARD THE TOTAL SYNTHESIS OF (-)-GONIOMITINE.

Pritchett Beau P BP Kikuchi Jun J Numajiri Yoshitaka Y Stoltz Brian M BM

Heterocycles 20170215 2

A Fischer indolization strategy toward the core of (-)-goniomitine is reported. Initial investigations into the Pd-catalyzed asymmetric allylic alkylation of dihydropyrido[1,2-<i>a</i>]indolone (DHPI) substrates are also discussed. ...[more]

PMID: 28706345

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