Recycling and Self-Healing of Polybenzoxazines with Dynamic Sulfide Linkages.
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ABSTRACT: In this work, a recycling and self-healing strategy for polybenzoxazines through both S-S bond cleavage-reformation reaction and supramolecular attractions is described. Both recyclable and self-healable polybenzoxazines can be prepared from low cost chemicals with a simple procedure in only 30 minutes. For this purpose, inverse vulcanization of poly(propylene oxide)benzoxazine (PPOB) and diallybenzoxazine (B-al) with elemental sulfur was performed at 185 °C. The obtained cross-linked polymer films exhibited thermally driven recycling ability up to 5 cycles. Moreover, the self-healing ability of a test specimen was shown. Spectral characterizations, thermal stability and fracture toughness of the films were investigated after each recycling.
SUBMITTER: Arslan M
PROVIDER: S-EPMC5507923 | biostudies-literature |
REPOSITORIES: biostudies-literature
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