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Thermally assisted self-healing behavior of anhydride modified polybenzoxazines based on transesterification.

ABSTRACT: A self-healing polybenzoxazine is synthesized solely based on dynamic ester bonds. For this purpose, an anhydride (succinic anhydride) was added into bisphenol F derived benzoxazine monomer before thermocuring. Owing to the transesterification of newly formed ester bonds, the thermoset network behaves as a thermoplastic at 140?°C in the presence of Zn (Ac)2, and shows self-healing properties even after multiple damage-healing cycles. Furthermore, kinetics study indicates that the transesterification is a first-order reaction and the activation energy is about 135.4?kJ/mol. This study proposes a facile and economical way to prepare self-healing polybenzoxazine. It has promising applications in coating, adhesive, and other smart materials that rely on structurally dynamic polymers.

SUBMITTER: Fu F

PROVIDER: S-EPMC6037739 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature

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Thermally assisted self-healing behavior of anhydride modified polybenzoxazines based on transesterification.

Fu Feiya F Huang Meiqi M Zhang Weilan W Zhao Yang Y Liu Xiangdong X

Scientific reports 20180709 1

A self-healing polybenzoxazine is synthesized solely based on dynamic ester bonds. For this purpose, an anhydride (succinic anhydride) was added into bisphenol F derived benzoxazine monomer before thermocuring. Owing to the transesterification of newly formed ester bonds, the thermoset network behaves as a thermoplastic at 140 °C in the presence of Zn (Ac)<sub>2</sub>, and shows self-healing properties even after multiple damage-healing cycles. Furthermore, kinetics study indicates that the tran ...[more]

PMID: 29985408

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