Ontology highlight
ABSTRACT:
SUBMITTER: Chen WB
PROVIDER: S-EPMC5526642 | biostudies-literature | 2016 Jun
REPOSITORIES: biostudies-literature
Advanced synthesis & catalysis 20160607 13
The use of electron-poor, fluoro-containing arylboronic acids as general coupling partners for nickel(0) /tricyclohexylphosphine-catalyzed cross-coupling of aryl arenesulfonates is described. Electron-poor fluoro-containing arylboronic acids were found to react, faster than electron-rich/neutral arylboronic acids, with (4-methoxyphenyl)(4-methylbenzenesulfonato-κ<i>O</i>)bis(tricyclohexylphosphine)nickel. Bis(1,5-cyclooctadiene)nickel(0)/tricyclohexylphosphine, (4-methoxyphenyl)(4-methylbenzenes ...[more]