Ontology highlight
ABSTRACT:
SUBMITTER: Tang ZY
PROVIDER: S-EPMC2531206 | biostudies-literature | 2006 Mar
REPOSITORIES: biostudies-literature
The Journal of organic chemistry 20060301 5
Room-temperature Ni(0)-catalyzed cross-coupling reactions of deactivated aryl chlorides with arylboronic acids with inexpensive triphenylphosphine (PPh3) as a supporting ligand have been accomplished in good to excellent yields. Air-stable Ni(PPh3)2Cl2 has also been established as catalyst precursor, and highly active nickel catalysts were obtained when the reduction of Ni(PPh3)2Cl2 with n-BuLi was carried out in the presence of an aryl chloride. ...[more]