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Redox-promoted associative assembly of metal-organic materials.

ABSTRACT: We develop an associative synthesis of metal-organic materials that combines solid-state metal oxidation and coordination-driven self-assembly into a one-step, waste-free transformation. The methodology hinges on the unique reactivity of ortho-quinones, which we introduce as versatile oxidants for mechanochemical synthesis. Our strategy opens a previously unexplored route to paramagnetic metal-organic materials from elementary metals.

SUBMITTER: Glavinovic M

PROVIDER: S-EPMC5530005 | biostudies-literature | 2016 Jan

REPOSITORIES: biostudies-literature

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Redox-promoted associative assembly of metal-organic materials.

Glavinović Martin M Qi Feng F Katsenis Athanassios D AD Friščić Tomislav T Lumb Jean-Philip JP

Chemical science 20151009 1

We develop an associative synthesis of metal-organic materials that combines solid-state metal oxidation and coordination-driven self-assembly into a one-step, waste-free transformation. The methodology hinges on the unique reactivity of <i>ortho</i>-quinones, which we introduce as versatile oxidants for mechanochemical synthesis. Our strategy opens a previously unexplored route to paramagnetic metal-organic materials from elementary metals. ...[more]

PMID: 28791114

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