Ontology highlight
ABSTRACT:
SUBMITTER: Brazzolotto D
PROVIDER: S-EPMC5531755 | biostudies-literature | 2017 Jul
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20170609 28
This study deals with the unprecedented reactivity of dinuclear non-heme Mn<sup>II</sup> -thiolate complexes with O<sub>2</sub> , which dependent on the protonation state of the initial Mn<sup>II</sup> dimer selectively generates either a di-μ-oxo or μ-oxo-μ-hydroxo Mn<sup>IV</sup> complex. Both dimers have been characterized by different techniques including single-crystal X-ray diffraction and mass spectrometry. Oxygenation reactions carried out with labeled <sup>18</sup> O<sub>2</sub> unambig ...[more]