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Red and green colors emitting spherical-shaped calcium molybdate nanophosphors for enhanced latent fingerprint detection.


ABSTRACT: We report the synthesis of spherical-shaped rare-earth (Eu3+ and Tb3+) ions doped CaMoO4 nanoparticles in double solvents (IPA and H2O) with the help of autoclave. The X-ray diffraction patterns well match with the standard values and confirm the crystallization in a tetragonal phase with an I41/a (88) space group. The luminescence spectra exhibit the strong red and green emissions from Eu3+ and Tb3+ ions doped samples, respectively. The X-ray photoelectron spectroscopy results show the oxidation states of all the elements present in the sample. The temperature-dependent luminescence spectra reveal the stability of Eu3+ and Tb3+ ions doped samples. The red- and green-emitting Eu3+ and Tb3+ ions doped CaMoO4 samples were used for detection and enhancement of latent fingerprints which are the common evidences found at crime scenes. The enhanced latent fingerprints obtained on different surfaces have high contrast with low background interference. The minute details of the fingerprint which are useful for individualization are clearly observed with the help of these nanopowders.

SUBMITTER: Bharat LK 

PROVIDER: S-EPMC5599674 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature

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Red and green colors emitting spherical-shaped calcium molybdate nanophosphors for enhanced latent fingerprint detection.

Bharat L Krishna LK   Raju G Seeta Rama GSR   Yu Jae Su JS  

Scientific reports 20170914 1


We report the synthesis of spherical-shaped rare-earth (Eu<sup>3+</sup> and Tb<sup>3+</sup>) ions doped CaMoO<sub>4</sub> nanoparticles in double solvents (IPA and H<sub>2</sub>O) with the help of autoclave. The X-ray diffraction patterns well match with the standard values and confirm the crystallization in a tetragonal phase with an I4<sub>1</sub>/a (88) space group. The luminescence spectra exhibit the strong red and green emissions from Eu<sup>3+</sup> and Tb<sup>3+</sup> ions doped samples,  ...[more]

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