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Deterministic optical polarisation in nitride quantum dots at thermoelectrically cooled temperatures.

ABSTRACT: We report the successful realisation of intrinsic optical polarisation control by growth, in solid-state quantum dots in the thermoelectrically cooled temperature regime (?200?K), using a non-polar InGaN system. With statistically significant experimental data from cryogenic to high temperatures, we show that the average polarisation degree of such a system remains constant at around 0.90, below 100?K, and decreases very slowly at higher temperatures until reaching 0.77 at 200?K, with an unchanged polarisation axis determined by the material crystallography. A combination of Fermi-Dirac statistics and k·p theory with consideration of quantum dot anisotropy allows us to elucidate the origin of the robust, almost temperature-insensitive polarisation properties of this system from a fundamental perspective, producing results in very good agreement with the experimental findings. This work demonstrates that optical polarisation control can be achieved in solid-state quantum dots at thermoelectrically cooled temperatures, thereby opening the possibility of polarisation-based quantum dot applications in on-chip conditions.

SUBMITTER: Wang T

PROVIDER: S-EPMC5608953 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature

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Deterministic optical polarisation in nitride quantum dots at thermoelectrically cooled temperatures.

Wang Tong T Puchtler Tim J TJ Patra Saroj K SK Zhu Tongtong T Jarman John C JC Oliver Rachel A RA Schulz Stefan S Taylor Robert A RA

Scientific reports 20170921 1

We report the successful realisation of intrinsic optical polarisation control by growth, in solid-state quantum dots in the thermoelectrically cooled temperature regime (≥200 K), using a non-polar InGaN system. With statistically significant experimental data from cryogenic to high temperatures, we show that the average polarisation degree of such a system remains constant at around 0.90, below 100 K, and decreases very slowly at higher temperatures until reaching 0.77 at 200 K, with an unchang ...[more]

PMID: 28935981

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Project description:Toxic metals present in drinking water pose a serious threat to the environment and human beings when present in abundance. In this work, we investigated the sensing ability of quantum dots (pristine CQDs, boron/nitrogen/sulphur (B/N/S)-doped CQDs, and BNQDs) of various sizes and morphologies (rectangular, circular, and triangular) towards toxic metals such as arsenic (As), cobalt (Co), nickel (Ni), copper (Cu), and lead (Pb) using quantum chemical density functional theory calculations in both gas and water phases. We probed the structural, electronic, and optical properties of the QDs. All the modelled QDs are energetically stable. Frontier molecular orbital analysis predicted that BNQDs are more chemically stable than all other CQDs. UV-vis absorption and Raman spectra analyses helped to understand the optical properties of all the QDs. Further, adsorption studies revealed that triangular pristine CQDs and sulphur-doped CQDs show higher adsorption affinity towards the toxic metals. The magnitude of adsorption energies follows the trend Ni > Pb > As > Cu > Co in most of the QDs. Several pristine and doped CQDs exhibited chemisorption towards the toxic metals, and hence, they can be used as adsorbents. However, a majority of BNQDs showed physisorption towards the metals, and therefore, they can be used as efficient optical sensors compared to CQDs. Further, the sensing ability of the QDs was explored through optical phenomena such as changes in UV-vis absorption spectra and fluorescence after metal adsorption. When compared to pristine CQDs and B/N/S-doped CQDs, metal complexation caused significant changes in the UV-vis absorbance peak intensities in BNQDs along with peak shifts. Moreover, metal interaction with the QDs increased their fluorescence lifetime with the highest values observed in Co-adsorbed triangular H18C46 (152.30 ns), Pb-adsorbed rectangular H15C30S (21.29 ns), and As-adsorbed circular B27N27H18 (2.99 μs) among pristine CQDs, B/N/S-doped CQDs, and BNQDs, respectively. Overall, we believe that our first-of-its-kind computational prediction of the optical sensing ability of tailor-made zero-dimensional systems such as QDs will be a great aid for experimentalists in designing novel and rapid optical probes to detect toxic metals in drinking water.

Dataset Information

Deterministic optical polarisation in nitride quantum dots at thermoelectrically cooled temperatures.

Publications

Deterministic optical polarisation in nitride quantum dots at thermoelectrically cooled temperatures.

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