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Wet-Chemical Synthesis of 3D Stacked Thin Film Metal-Oxides for All-Solid-State Li-Ion Batteries.


ABSTRACT: By ultrasonic spray deposition of precursors, conformal deposition on 3D surfaces of tungsten oxide (WO₃) negative electrode and amorphous lithium lanthanum titanium oxide (LLT) solid-electrolyte has been achieved as well as an all-solid-state half-cell. Electrochemical activity was achieved of the WO₃ layers, annealed at temperatures of 500 °C. Galvanostatic measurements show a volumetric capacity (415 mAh·cm-3) of the deposited electrode material. In addition, electrochemical activity was shown for half-cells, created by coating WO₃ with LLT as the solid-state electrolyte. The electron blocking properties of the LLT solid-electrolyte was shown by ferrocene reduction. 3D depositions were done on various micro-sized Si template structures, showing fully covering coatings of both WO₃ and LLT. Finally, the thermal budget required for WO₃ layer deposition was minimized, which enabled attaining active WO₃ on 3D TiN/Si micro-cylinders. A 2.6-fold capacity increase for the 3D-structured WO₃ was shown, with the same current density per coated area.

SUBMITTER: van den Ham EJ 

PROVIDER: S-EPMC5615726 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature

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Wet-Chemical Synthesis of 3D Stacked Thin Film Metal-Oxides for All-Solid-State Li-Ion Batteries.

van den Ham Evert Jonathan EJ   Maino Giulia G   Bonneux Gilles G   Marchal Wouter W   Elen Ken K   Gielis Sven S   Mattelaer Felix F   Detavernier Christophe C   Notten Peter H L PHL   Van Bael Marlies K MK   Hardy An A  

Materials (Basel, Switzerland) 20170912 9


By ultrasonic spray deposition of precursors, conformal deposition on 3D surfaces of tungsten oxide (WO₃) negative electrode and amorphous lithium lanthanum titanium oxide (LLT) solid-electrolyte has been achieved as well as an all-solid-state half-cell. Electrochemical activity was achieved of the WO₃ layers, annealed at temperatures of 500 °C. Galvanostatic measurements show a volumetric capacity (415 mAh·cm<sup>-3</sup>) of the deposited electrode material. In addition, electrochemical activi  ...[more]

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