Ontology highlight
ABSTRACT:
SUBMITTER: Won WS
PROVIDER: S-EPMC5621591 | biostudies-literature | 2013
REPOSITORIES: biostudies-literature
Won Walter S WS Knapp Spencer S
Journal of sulphur chemistry 20120810 1-2
A short synthetic route to β,d-arabinofuranosyl 1-C-sulfonic acid (<b>7</b>), a possible biomimetic for the arabinofuranosyl anomeric phosphate, is described. The furanosyl 1-<i>C</i>-sulfonate was prepared by buffered DMDO oxidation of an <i>S</i>-acetyl-1-thio-β-arabinofuranose derivative. Deprotection under mild conditions allowed isolation of the free sulfonic acid without desulfonylation. ...[more]