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Composition-dependent nanoelectronics of amido-phenazines: non-volatile RRAM and WORM memory devices.


ABSTRACT: A metal-free three component cyclization reaction with amidation is devised for direct synthesis of DFT-designed amido-phenazine derivative bearing noncovalent gluing interactions to fabricate organic nanomaterials. Composition-dependent organic nanoelectronics for nonvolatile memory devices are discovered using mixed phenazine-stearic acid (SA) nanomaterials. We discovered simultaneous two different types of nonmagnetic and non-moisture sensitive switching resistance properties of fabricated devices utilizing mixed organic nanomaterials: (a) sample-1(8:SA?=?1:3) is initially off, turning on at a threshold, but it does not turn off again with the application of any voltage, and (b) sample-2 (8:SA?=?3:1) is initially off, turning on at a sharp threshold and off again by reversing the polarity. No negative differential resistance is observed in either type. These samples have different device implementations: sample-1 is attractive for write-once-read-many-times memory devices, such as novel non-editable database, archival memory, electronic voting, radio frequency identification, sample-2 is useful for resistive-switching random access memory application.

SUBMITTER: Maiti DK 

PROVIDER: S-EPMC5645374 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature

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Composition-dependent nanoelectronics of amido-phenazines: non-volatile RRAM and WORM memory devices.

Maiti Dilip K DK   Debnath Sudipto S   Nawaz Sk Masum SM   Dey Bapi B   Dinda Enakhi E   Roy Dipanwita D   Ray Sudipta S   Mallik Abhijit A   Hussain Syed A SA  

Scientific reports 20171017 1


A metal-free three component cyclization reaction with amidation is devised for direct synthesis of DFT-designed amido-phenazine derivative bearing noncovalent gluing interactions to fabricate organic nanomaterials. Composition-dependent organic nanoelectronics for nonvolatile memory devices are discovered using mixed phenazine-stearic acid (SA) nanomaterials. We discovered simultaneous two different types of nonmagnetic and non-moisture sensitive switching resistance properties of fabricated de  ...[more]

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