Browse
Submit Data
Databases
API
Help

Dataset Information

14 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Novel approach to hydroxy-group-containing porous organic polymers from bisphenol A.

ABSTRACT: We successfully employed bisphenol A and several different formyl-containing monomers as useful building blocks to construct a series of hydroxy-group-containing porous organic polymers in a sealed tube at high temperature. Fourier transform infrared and solid-state ¹³C CP/MAS NMR spectroscopy are utilized to characterize the possible structure of the obtained polymers. The highest Brunauer-Emmet-Teller specific surface area of the phenolic-resin porous organic polymers (PPOPs) is estimated to be 920 m² g^-1. The PPOPs exhibit a highest carbon dioxide uptake (up to 15.0 wt % (273 K) and 8.8 wt % (298 K) at 1.0 bar), and possess moderate hydrogen storage capacities ranging from 1.28 to 1.04 wt % (77 K) at 1.0 bar. Moreover, the highest uptake of methane for the PPOPs is measured as 4.3 wt % (273 K) at 1.0 bar.

SUBMITTER: Wang T

PROVIDER: S-EPMC5647697 | biostudies-literature | 2017

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Novel approach to hydroxy-group-containing porous organic polymers from bisphenol A.

Wang Tao T Zhao Yan-Chao YC Zhang Li-Min LM Cui Yi Y Zhang Chang-Shan CS Han Bao-Hang BH

Beilstein journal of organic chemistry 20171012

We successfully employed bisphenol A and several different formyl-containing monomers as useful building blocks to construct a series of hydroxy-group-containing porous organic polymers in a sealed tube at high temperature. Fourier transform infrared and solid-state <sup>13</sup>C CP/MAS NMR spectroscopy are utilized to characterize the possible structure of the obtained polymers. The highest Brunauer-Emmet-Teller specific surface area of the phenolic-resin porous organic polymers (PPOPs) is est ...[more]

PMID: 29062434

Similar Datasets

Porous inorganic-organic shape memory polymers.

Project description:Thermoresponsive shape memory polymers (SMPs) are a type of stimuli-sensitive materials that switch from a temporary shape back to their permanent shape upon exposure to heat. While the majority of SMPs have been fabricated in the solid form, porous SMP foams exhibit distinct properties and are better suited for certain applications, including some in the biomedical field. Like solid SMPs, SMP foams have been restricted to a limited group of organic polymer systems. In this study, we prepared inorganic-organic SMP foams based on the photochemical cure of a macromer comprised of inorganic polydimethylsiloxane (PDMS) segments and organic poly(?-caprolactone) (PCL) segments, diacrylated PCL(40)-block-PDMS(37)-block-PCL(40). To achieve tunable pore size with high interconnectivity, the SMP foams were prepared via a refined solvent-casting/particulate-leaching (SCPL) method. By varying design parameters such as degree of salt fusion, macromer concentration in the solvent and salt particle size, the SMP foams with excellent shape memory behavior and tunable pore size, pore morphology, and modulus were obtained.

| S-EPMC3433079 | biostudies-literature

Ionic Porous Organic Polymers Based on Functionalized Tetraarylborates.

Project description:Lithium tetrakis(4-boronatoaryl)borates were subjected to polycondensation reactions with selected polyhydroxyl monomers such as 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) and 2,3,6,7-tetrahydroxy-9,10-dimethylanthracene (THDMA). Obtained boronate-type ionic porous polymers TAB1-4 were characterized by PXRD, 6Li and 11B magic-angle spinning nuclear magnetic resonance (MAS NMR), FT-IR, SEM, and TGA. They exhibit relatively good sorption of H2 (up to 75 cm3/g STP), whereas N2 uptake at 77 K for lower pressure range is relatively poor (up to 50 cm3/g STP below P/P0 = 0.8). In addition, the effect of elongation of aryl arms in the tetraarylborate core on the materials' properties was studied. Thus, it was found that replacement of the 4-boronatophenyl with 4-boronatobiphenylyl group has a negative impact on the sorption characteristics.

| S-EPMC6630441 | biostudies-literature

A Facile Approach to Prepare Multiple Heteroatom-Doped Carbon Materials from Imine-Linked Porous Organic Polymers.

Project description:In this paper, we proposed a new strategy to prepare multiple heteroatom doped (N, P-doped) porous carbon materials with high surface area of ~1,535?m2 g-1 simply by pyrolysis of imine-linked porous organic polymers (POPs) synthesized via Schiff base condensation. The strategy is simple without any post-processing and various heteroatoms could be involved. Scanning electron microscopy, Raman spectra, Nitrogen gas adsorption-desorption, X-ray photoelectron spectroscopy have been used to characterize the morphology, the structure and the composition of the materials. The multiple heteroatom doped porous carbon materials also display high electrocatalytic performance as exampled by the application in oxygen reduction, which showed the catalyst favors 4-electron transfer during the process, along with superior stability and higher tolerance to methanol as compared to the Pt/C. These results indicate the present method is promising for the preparation of multi-heteroatom doped carbon materials in the application of electrocatalysis.

| S-EPMC5844873 | biostudies-other

Pyrene-Based Fluorescent Porous Organic Polymers for Recognition and Detection of Pesticides.

Project description:Eating vegetables with pesticide residues over a long period of time causes serious adverse effects on the human body, such as acute poisoning, chronic poisoning, and endocrine system interference. To achieve the goal of a healthy society, it is an urgent issue to find a simple and effective method to detect organic pesticides. In this work, two fluorescent porous organic polymers, LNU-45 and LNU-47 (abbreviation for Liaoning University), were prepared using π-conjugated dibromopyrene monomer and boronic acid compounds as building units through a Suzuki coupling reaction. Due to the large π-electron delocalization effect, the resulting polymers revealed enhanced fluorescence performance. Significantly, in sharp contrast with the planar π-conjugated polymer framework (LNU-47), the distorted conjugated structure (LNU-45) shows a higher specific surface area and provides a broad interface for analyte interaction, which is helpful to achieve rapid response and detection sensitivity. LNU-45 exhibits strong fluorescence emission at 469 nm after excitation at 365 nm in THF solution, providing strong evidence for its suitability as a luminescent chemosensor for organic pesticides. The fluorescence quenching coefficients of LNU-45 for trifluralin and dicloran were 5710 and 12,000 (LNU-47 sample by ca. 1.98 and 3.38 times), respectively. Therefore, LNU-45 serves as an effective "real-time" sensor for the detection of trifluralin and dicloran with high sensitivity and selectivity.

| S-EPMC8746865 | biostudies-literature

Nitrogen-Doped Carbons Derived from Imidazole-Based Cross-Linked Porous Organic Polymers.

Project description:Nitrogen-doped and heteroatom multi-doped carbon materials are considered excellent metal-free catalysts, superior catalyst supports for transition metal particles and single metal atoms (single-atom catalysts), as well as efficient sorbents for gas- and liquid-phase substances. Acid-catalyzed sol-gel polycondensation of hydroxybenzenes with heterocyclic aldehydes yields cross-linked thermosetting resins in the form of porous organic polymers (i.e., organic gels). Depending on the utilized hydroxybenzene (e.g., phenol, resorcinol, phloroglucinol, etc.) and heterocyclic aldehyde variety of heteroatom-doped organic polymers can be produced. Upon pyrolysis, highly porous and heteroatom-doped carbons are obtained. Herein, polycondensation of phloroglucinol with imidazole-2-carboxaldehyde (and other, similar heterocyclic aldehydes with two heteroatoms in the aromatic ring) is utilized to obtain porous, N-doped organic and carbon gels with N-content of up to 16.5 and 12 wt.%, respectively. Utilization of a heterocyclic aldehyde with two different heteroatoms yields dually-doped carbon materials. Upon pyrolysis, the porous polymers yield ultramicroporous N-doped and N,S co-doped carbons with specific surface areas of up to 800 m2g-1. The influence of the initial composition of reactants and the pyrolysis temperature on the structure and chemical composition of the final doped organic and carbon materials is studied in detail.

| S-EPMC7865342 | biostudies-literature

Aerogels of 1D Coordination Polymers: From a Non-Porous Metal-Organic Crystal Structure to a Highly Porous Material.

Project description:The processing of an originally non-porous 1D coordination polymer as monolithic gel, xerogel and aerogel is reported as an alternative method to obtain novel metal-organic porous materials, conceptually different to conventional crystalline porous coordination polymer (PCPs) or metal-organic frameworks (MOFs). Although the work herein reported is focused upon a particular kind of coordination polymer ([M(μ-ox)(4-apy)₂]n, M: Co(II), Ni(II)), the results are of interest in the field of porous materials and of MOFs, as the employed synthetic approach implies that any coordination polymer could be processable as a mesoporous material. The polymerization conditions were fixed to obtain stiff gels at the synthesis stage. Gels were dried at ambient pressure and at supercritical conditions to render well shaped monolithic xerogels and aerogels, respectively. The monolithic shape of the synthesis product is another remarkable result, as it does not require a post-processing or the use of additives or binders. The aerogels of the 1D coordination polymers are featured by exhibiting high pore volumes and diameters ranging in the mesoporous/macroporous regions which endow to these materials the ability to deal with large-sized molecules. The aerogel monoliths present markedly low densities (0.082⁻0.311 g·cm-3), an aspect of interest for applications that persecute light materials.

| S-EPMC6432558 | biostudies-literature

Hierarchically porous organic polymers: highly enhanced gas uptake and transport through templated synthesis.

Project description:Porous organic polymers (POPs) possessing meso- and micropores can be obtained by carrying out the polymerization inside a mesoporous silica aerogel template and then removing the template after polymerization. The total pore volume (tpv) and specific surface area (ssa) can be greatly enhanced by modifying the template (up to 210% increase for tpv and 73% for ssa) as well as by supercritical processing of the POPs (up to an additional 142% increase for tpv and an additional 32% for ssa) to include larger mesopores. The broad range of pores allows for faster transport of molecules through the hierarchically porous POPs, resulting in increased diffusion rates and faster gas uptake compared to POPs with only micropores.

| S-EPMC5586205 | biostudies-literature

Application of Covalent Organic Porous Polymers-Functionalized Basalt Fibers for in-Tube Solid-Phase Microextraction.

Project description:To establish an online analytical method towards estrogenic pollutants, a covalent organic porous polymer (COP) was in-situ synthesized on the surface of basalt fibers (BFs) for in-tube solid-phase microextraction (IT-SPME). The extraction tube, obtained via placing the modified BFs into a polyetheretherketone tube, was combined with high-performance liquid chromatography (HPLC) to achieve online IT-SPME-HPLC analysis. The important parameters, including sampling volume, sampling rate, organic solvent content and desorption time, were carefully investigated. Under the optimized conditions, the online analytical method was established for five estrogenic targets, with low limits of detection (0.001-0.005 μg/L), high enrichment factors (1800-2493), wide linear ranges (0.003-20, 0.015-20 μg/L) and satisfactory repeatability. It was successfully applied to detect five estrogens in a wastewater sample and a water sample in a polycarbonate cup. The BFs functionalized with COPs displayed excellent extraction effect for estrogenic pollutants, furthermore it has great potential in sample preparation or other fields.

| S-EPMC7763957 | biostudies-literature

Novel Conjugated Polymers Containing 3-(2-Octyldodecyl)thieno[3,2-b]thiophene as a π-Bridge for Organic Photovoltaic Applications.

Project description:3-(2-Octyldodecyl)thieno[3,2-b]thiophen was successfully synthesized as a new π-bridge with a long branched side alkyl chain. Two donor-π-bridge-acceptor type copolymers were designed and synthesized by combining this π-bridge structure, a fluorinated benzothiadiazole acceptor unit, and a thiophene or thienothiophene donor unit, (PT-ODTTBT or PTT-ODTTBT respectively) through Stille polymerization. Inverted OPV devices with a structure of ITO/ZnO/polymer:PC71BM/MoO3/Ag were fabricated by spin-coating in ambient atmosphere or N2 within a glovebox to evaluate the photovoltaic performance of the synthesized polymers (effective active area: 0.09 cm2). The PTT-ODTTBT:PC71BM-based structure exhibited the highest organic photovoltaic (OPV) device performance, with a maximum power conversion efficiency (PCE) of 7.05 (6.88 ± 0.12)%, a high short-circuit current (Jsc) of 13.96 mA/cm2, and a fill factor (FF) of 66.94 (66.47 ± 0.63)%; whereas the PT-ODTTBT:PC71BM-based device achieved overall lower device performance. According to GIWAXS analysis, both neat and blend films of PTT-ODTTBT exhibited well-organized lamellar stacking, leading to a higher charge carrier mobility than that of PT-ODTTBT. Compared to PT-ODTTBT containing a thiophene donor unit, PTT-ODTTBT containing a thienothiophene donor unit exhibited higher crystallinity, preferential face-on orientation, and a bicontinuous interpenetrating network in the film, which are responsible for the improved OPV performance in terms of high Jsc, FF, and PCE.

| S-EPMC7570215 | biostudies-literature

Porous Organic Polymers as Fire-Resistant Additives and Precursors for Hyperporous Carbon towards Oxygen Reduction Reactions.

Project description:Cyclotriphosphazene (CP) based porous organic polymers (POPs) have been designed and prepared. The introduction of CP into the porous skeleton endowed special thermal stability and outstanding flame retardancy to prepared polymers. The nonflammable level of PNK-CMP fabricated via the condensation of 2,2'-(1,4-phenylene)diacetonitrile (DAN) and hexakis(4-acetylphenoxy)cyclotriphosphazene (HACTP) through Knoevenagel reaction, in vertical burning tests reached V-2 class (UL-94) and the limiting oxygen index (LOI) reached 20.8?%. When used as additive, PNK-CMP could suppress the dissolving out of PEPA effectively, reducing environment pollution and improving the flame retardant efficiency. The POP and PEPA co-added PU (mPOP%: mPEPA%=5.0?%: 5.0?%) could not be ignited under simulated real-scale fire conditions. The nonflammable level of POP/PEPA/PU in vertical burning tests (UL-94) reached V-0 class with a LOI as high as 23.2?%. The smoke emission could also be suppressed, thus reducing the potential for flame spread and fire hazards. Furthermore, carbonization of PNK-CMP under the activation of KOH yield a hyperporous carbon (PNKA-800) with ultrahigh BET surface area (3001?m2?g-1) and ultramicropore size showing excellent ORR activity in alkaline conditions.

| S-EPMC7239271 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data