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Nitrogen-Doped Carbons Derived from Imidazole-Based Cross-Linked Porous Organic Polymers.

ABSTRACT: Nitrogen-doped and heteroatom multi-doped carbon materials are considered excellent metal-free catalysts, superior catalyst supports for transition metal particles and single metal atoms (single-atom catalysts), as well as efficient sorbents for gas- and liquid-phase substances. Acid-catalyzed sol-gel polycondensation of hydroxybenzenes with heterocyclic aldehydes yields cross-linked thermosetting resins in the form of porous organic polymers (i.e., organic gels). Depending on the utilized hydroxybenzene (e.g., phenol, resorcinol, phloroglucinol, etc.) and heterocyclic aldehyde variety of heteroatom-doped organic polymers can be produced. Upon pyrolysis, highly porous and heteroatom-doped carbons are obtained. Herein, polycondensation of phloroglucinol with imidazole-2-carboxaldehyde (and other, similar heterocyclic aldehydes with two heteroatoms in the aromatic ring) is utilized to obtain porous, N-doped organic and carbon gels with N-content of up to 16.5 and 12 wt.%, respectively. Utilization of a heterocyclic aldehyde with two different heteroatoms yields dually-doped carbon materials. Upon pyrolysis, the porous polymers yield ultramicroporous N-doped and N,S co-doped carbons with specific surface areas of up to 800 m²g^-1. The influence of the initial composition of reactants and the pyrolysis temperature on the structure and chemical composition of the final doped organic and carbon materials is studied in detail.

SUBMITTER: Kicinski W

PROVIDER: S-EPMC7865342 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature

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Nitrogen-Doped Carbons Derived from Imidazole-Based Cross-Linked Porous Organic Polymers.

Kiciński Wojciech W Dyjak Sławomir S

Molecules (Basel, Switzerland) 20210127 3

Nitrogen-doped and heteroatom multi-doped carbon materials are considered excellent metal-free catalysts, superior catalyst supports for transition metal particles and single metal atoms (single-atom catalysts), as well as efficient sorbents for gas- and liquid-phase substances. Acid-catalyzed sol-gel polycondensation of hydroxybenzenes with heterocyclic aldehydes yields cross-linked thermosetting resins in the form of porous organic polymers (i.e., organic gels). Depending on the utilized hydro ...[more]

PMID: 33514064

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Project description:Two novel carbons (MCs) derived from moxa floss of different storage years have been prepared by two low-cost and facile approaches, which are hydrothermal carbonization at a low temperature (200 °C) and direct pyrolysis at a moderate temperature (500 °C) followed by potassium hydroxide (KOH) activation strategy at a high temperature (800 °C), respectively. The physicochemical properties of MCs are investigated by Raman spectra, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and nitrogen adsorption-desorption isotherms. Results show that MCs derived from moxa floss of different storage years by two facile approaches possess different morphologies: MCs by hydrothermal carbonization (denoted as MC-1, MC-2 and MC-3) exhibit porous nanosheet structures, the highest specific surface area is about 1788.6 m2 g-1, and the largest total pore volumes is around 0.8170 cm3 g-1, while MCs by direct pyrolysis (denoted as MC-4, MC-5 and MC-6) have basically blocky and rod-like morphologies, the highest specific surface area is about 1628.0 m2 g-1, and the largest total pore volume is around 0.7058 cm3 g-1. However, despite the different morphologies, all MCs possess a similar hierarchical porous structure, numerous heteroatom groups and good electrical conductivity. Therefore, these low-cost, biomass-derived porous carbons with promising capacitive performance are used for supercapacitors application with high performance, for example, the as-assembled supercapacitor based on MC-5 exhibits a high specific capacitance of 288.3 F g-1 at 0.25 A g-1, an excellent rate performance of 243.5 F g-1 even at 30 A g-1 with 84.5% capacitance retention of its initial specific capacitance, and an outstanding long-term cycling stability with 98.7% capacitance retention after 10 000 cycles at 5 A g-1. Furthermore, the maximum energy density for these supercapacitors with an aqueous electrolyte in a two-electrode system is about 10.0 W h kg-1 at a power density of 70.3 W kg-1. Therefore, this work opens up a whole new field for the applications of moxa floss and this novel concept of moxa floss use is an extremely promising strategy for developing high-performance carbons with porous structures and heteroatom-doping from renewable sources.

Dataset Information

Nitrogen-Doped Carbons Derived from Imidazole-Based Cross-Linked Porous Organic Polymers.

Publications

Nitrogen-Doped Carbons Derived from Imidazole-Based Cross-Linked Porous Organic Polymers.

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