Ontology highlight
ABSTRACT:
SUBMITTER: Mizugaki T
PROVIDER: S-EPMC5656575 | biostudies-literature | 2017 Oct
REPOSITORIES: biostudies-literature
Mizugaki Tomoo T Togo Keito K Maeno Zen Z Mitsudome Takato T Jitsukawa Koichiro K Kaneda Kiyotomi K
Scientific reports 20171025 1
Highly selective hydrogenative carbon-carbon bond scission of biomass-derived platform oxygenates was achieved with a cerium oxide-supported ruthenium nanoparticle catalyst in water. The present catalyst enabled the selective cleavage of carbon-carbon σ bonds adjacent to carboxyl, ester, and hydroxymethyl groups, opening new eight synthetic routes to valuable chemicals from biomass derivatives. The high selectivity for such carbon-carbon bond scission over carbon-oxygen bonds was attributed to t ...[more]