HBr-DMPU: The First Aprotic Organic Solution of Hydrogen Bromide.
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ABSTRACT:
SUBMITTER: Li Z
PROVIDER: S-EPMC5682921 | biostudies-literature | 2017 Sep
REPOSITORIES: biostudies-literature
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HBr-DMPU: The First Aprotic Organic Solution of Hydrogen Bromide.
Li Zhou Z Ebule Rene R Kostyo Jessica J Hammond Gerald B GB Xu Bo B
Chemistry (Weinheim an der Bergstrasse, Germany) 20170816 52
HBr and DMPU (1,3-dimethyl-3,4,5,6-tetrahydro-2-pyrimidinone) form a room-temperature-stable complex that provides a mild, effective, and selective hydrobrominating reagent toward alkynes, alkenes, and allenes. HBr-DMPU could also replace other halogenating reagents in the halo-Prins reaction, ether cleavage, and deoxy-bromination reactions. ...[more]
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