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Phenolic condensation and facilitation of fluorescent carbon dot formation: a mechanism study.

ABSTRACT: Fluorescent carbon dots have received considerable attention as a result of their accessibility and potential applications. Although several prior studies have demonstrated that nearly any organic compound can be converted into carbon dots by chemical carbonization processes, mechanisms explaining the formation of carbon dots still remain unclear. Herein, we propose a seed-growth mechanism of carbon dot formation facilitated by ferulic acid, a widespread and naturally occurring phenolic compound in the seeds of Ocimum basilicum (basil). Ferulic acid triggers the local condensation of polysaccharide chains and forms catalytic core regions resulting in nanoscale carbonization. Our study indicates that carbon dots generated from natural sources might share the similar mechanism of phenolic compound mediated nanoscale condensation followed by core carbonization.

SUBMITTER: Lee K

PROVIDER: S-EPMC5687888 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature

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Phenolic condensation and facilitation of fluorescent carbon dot formation: a mechanism study.

Lee Kyueui K Park Eunsook E Lee Haesung A HA Sugnaux Caroline C Shin Mikyung M Jeong Chan Jin CJ Lee Jeehee J Messersmith Phillip B PB Park Sung Young SY Lee Haeshin H

Nanoscale 20171101 43

Fluorescent carbon dots have received considerable attention as a result of their accessibility and potential applications. Although several prior studies have demonstrated that nearly any organic compound can be converted into carbon dots by chemical carbonization processes, mechanisms explaining the formation of carbon dots still remain unclear. Herein, we propose a seed-growth mechanism of carbon dot formation facilitated by ferulic acid, a widespread and naturally occurring phenolic compound ...[more]

PMID: 29071324

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Correction: Fluorescent carbon dot-molecular salt hydrogels.

Project description:[This corrects the article DOI: 10.1039/C5SC01859E.].

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