Ontology highlight
ABSTRACT:
SUBMITTER: Ma Y
PROVIDER: S-EPMC5703425 | biostudies-literature | 2017 Jul
REPOSITORIES: biostudies-literature
Ma Yuzhi Y Yun Young K YK Wondergem Nee Lukesh Julie J Sar Anobick A Gone Jayapal Reddy JR Lindeman Sergey S Donaldson William A WA
Tetrahedron 20170615 30
The reaction of tricarbonyl and (dicarbonyl)triphenylphosphine (1-methoxycarbonyl-pentadientyl)iron(1+) cations <b>7</b> and <b>8</b> with methyl lithium, NaBH<sub>3</sub>CN, or potassium phthalimide affords (pentenediyl)iron complexes <b>9a-c</b> and <b>11a-b</b>, while reaction with dimethylcuprate, gave (<i>E</i>,<i>Z</i>-diene)iron complexes <b>10</b> and <b>12</b>. Oxidatively induced-reductive elimination of <b>9a-c</b> gave vinylcyclopropanecarboxylates <b>17a-c</b>. The optically active ...[more]