Ontology highlight
ABSTRACT:
SUBMITTER: Hong S
PROVIDER: S-EPMC5711427 | biostudies-literature | 2017 Oct
REPOSITORIES: biostudies-literature
Hong Seungwoo S Lu Xiaoyan X Lee Yong-Min YM Seo Mi Sook MS Ohta Takehiro T Ogura Takashi T Clémancey Martin M Maldivi Pascale P Latour Jean-Marc JM Sarangi Ritimukta R Nam Wonwoo W
Journal of the American Chemical Society 20171004 41
A mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [Fe<sup>V</sup>(NTs)(TAML)]<sup>-</sup> (1), was oxidized by one-electron oxidants, affording formation of an iron(V)-imido TAML cation radical species, [Fe<sup>V</sup>(NTs)(TAML<sup>+•</sup>)] (2); 2 is a diamagnetic (S = 0) complex, resulting from the antiferromagnetic coupling of the low-spin iron(V) ion (S = 1/2) with the one-electron oxidized ligand (TAML<sup>+•</sup>). 2 is a competent oxidant in C- ...[more]