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Homochiral coordination polymer with infinite double-stranded helices.

ABSTRACT: Hydrothermal reaction of 4,4-trimethylenedipyridine (tmdp) with ZnI2 under 175 degrees C yields a novel compound, {[Zn2I4(tmdp)2]n.[Zn2I4(tmdp)2]n}, which has a chiral infinite double-stranded helical structure consisting of two single-stranded helices of the same handedness.

SUBMITTER: Han L 

PROVIDER: S-EPMC5715663 | biostudies-literature | 2007 Mar

REPOSITORIES: biostudies-literature

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Homochiral coordination polymer with infinite double-stranded helices.

Han Lei L   Valle Henry H   Bu Xianhui X  

Inorganic chemistry 20070207 5

Hydrothermal reaction of 4,4-trimethylenedipyridine (tmdp) with ZnI2 under 175 degrees C yields a novel compound, {[Zn2I4(tmdp)2]n.[Zn2I4(tmdp)2]n}, which has a chiral infinite double-stranded helical structure consisting of two single-stranded helices of the same handedness. ...[more]

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