Ontology highlight
ABSTRACT:
SUBMITTER: Xue H
PROVIDER: S-EPMC6648636 | biostudies-literature | 2019 Jun
REPOSITORIES: biostudies-literature
Xue Hui H Cao Junze J Zhao Liang L Hao Haigang H Hong Maochun M
ACS omega 20190620 6
A novel conformation-driven self-assembly system from a one-dimensional polymer to a metal-organic double nanotube has been developed. DFT calculations indicate that the double nanotube with a <i>syn</i>-conformation of ligands is a thermodynamically favored stable product than a one-dimensional polymer. To the best of our knowledge, this is the first example of the infinite metal-organic double nanotube. In addition, a discrete M<sub>6</sub>L<sub>8</sub>-type cage has also been in situ self-ass ...[more]