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Conformation-Driven Self-Assembly: From a 1D Metal-Organic Polymer to an Infinite Double Nanotube.

ABSTRACT: A novel conformation-driven self-assembly system from a one-dimensional polymer to a metal-organic double nanotube has been developed. DFT calculations indicate that the double nanotube with a syn-conformation of ligands is a thermodynamically favored stable product than a one-dimensional polymer. To the best of our knowledge, this is the first example of the infinite metal-organic double nanotube. In addition, a discrete M6L8-type cage has also been in situ self-assembled from rationally selected building blocks.

SUBMITTER: Xue H 

PROVIDER: S-EPMC6648636 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

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Conformation-Driven Self-Assembly: From a 1D Metal-Organic Polymer to an Infinite Double Nanotube.

Xue Hui H   Cao Junze J   Zhao Liang L   Hao Haigang H   Hong Maochun M  

ACS omega 20190620 6

A novel conformation-driven self-assembly system from a one-dimensional polymer to a metal-organic double nanotube has been developed. DFT calculations indicate that the double nanotube with a <i>syn</i>-conformation of ligands is a thermodynamically favored stable product than a one-dimensional polymer. To the best of our knowledge, this is the first example of the infinite metal-organic double nanotube. In addition, a discrete M<sub>6</sub>L<sub>8</sub>-type cage has also been in situ self-ass  ...[more]

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