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ABSTRACT:
SUBMITTER: Jimenez J
PROVIDER: S-EPMC5728992 | biostudies-literature | 2017 Mar
REPOSITORIES: biostudies-literature
Jimenez Jorge J Chakraborty Indranil I Rojas-Andrade Mauricio M Mascharak Pradip K PK
Journal of inorganic biochemistry 20161210
Two new silver(I) complexes, namely [Ag(qyAm)<sub>2</sub>](CF<sub>3</sub>SO<sub>3</sub>) (1) and [Ag(qyTAm)<sub>2</sub>](CF<sub>3</sub>SO<sub>3</sub>) (2), (qyAm=2-(quinonyl)iminoadamantane, qyTAm=2-(quinonyl)iminotriazaadamantane) have been synthesized and characterized by elemental analyses, <sup>1</sup>H NMR, IR, electronic absorption spectroscopy, and X-ray diffraction. The coordination geometry of the silver center in both complexes is distorted tetrahedral where their respective qyAm and q ...[more]