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A New Low-Temperature Electrochemical Hydrocarbon and NOx Sensor.

ABSTRACT: In this article, a new investigation on a low-temperature electrochemical hydrocarbon and NOx sensor is presented. Based on the mixed-potential-based sensing scheme, the sensor is constructed using platinum and metal oxide electrodes, along with an Yttria-Stabilized Zirconia (YSZ)/Strontium Titanate (SrTiO?) thin-film electrolyte. Unlike traditional mixed-potential sensors which operate at higher temperatures (>400 °C), this potentiometric sensor operates at 200 °C with dominant hydrocarbon (HC) and NOx response in the open-circuit and biased modes, respectively. The possible low-temperature operation of the sensor is speculated to be primarily due to the enhanced oxygen ion conductivity of the electrolyte, which may be attributed to the space charge effect, epitaxial strain, and atomic reconstruction at the interface of the YSZ/STO thin film. The response and recovery time for the NOx sensor are found to be 7 s and 8 s, respectively. The sensor exhibited stable response even after 120 days of testing, with an 11.4% decrease in HC response and a 3.3% decrease in NOx response.

SUBMITTER: Sekhar PK

PROVIDER: S-EPMC5750761 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature

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A New Low-Temperature Electrochemical Hydrocarbon and NO<sub>x</sub> Sensor.

Sekhar Praveen Kumar PK Moore Zachary Z Aravamudhan Shyam S Khosla Ajit A Khosla Ajit A

Sensors (Basel, Switzerland) 20171129 12

In this article, a new investigation on a low-temperature electrochemical hydrocarbon and NO<sub>x</sub> sensor is presented. Based on the mixed-potential-based sensing scheme, the sensor is constructed using platinum and metal oxide electrodes, along with an Yttria-Stabilized Zirconia (YSZ)/Strontium Titanate (SrTiO₃) thin-film electrolyte. Unlike traditional mixed-potential sensors which operate at higher temperatures (>400 °C), this potentiometric sensor operates at 200 °C with dominant hydro ...[more]

PMID: 29186027

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Project description:This study presents an external temperature sensor assisted a new low power, time-interleave, wide dynamic range, and low DC drift photoplethysmography (PPG) signal acquisition system to obtain the accurate measurement of various bio signs in real-time. The designed chip incorporates a 2-bit control programmable transimpedance amplifier (TIA), a high order filter, a 3:8 programmable gain amplifier (PGA) and 2 × 2 organic light-emitting diode (OLED) driver. Temperature sensor is used herein to compensate the adverse effect of low-skin-temperature on the PPG signal quality. The analog front-end circuit is implemented in the integrated chip with chip area of 2008 μm × 1377 μm and fabricated via TSMC T18 process. With the standard 1.8 V, the experimental result shows that the measured current sensing range is 20 nA-100 uA. The measured dynamic range of the designed readout circuit is 80 dB. The estimated signal to noise ratio is 60 dB@1 uA, and the measured input referred noise is 60.2 pA/Hz½. The total power consumption of the designed chip is 31.32 µW (readout) + 1.62 mW (OLED driver@100% duty cycle). The non-invasive PPG sensor is applied to the wrist artery of the 40 healthy subjects for sensing the pulsation of the blood vessel. The experimental results show that for every 1 °C decrease in mean ambient temperature tends to 0.06 beats/min, 0.125 mmHg and 0.063 mmHg increase in hear rate (HR), systolic (SBP) and diastolic (DBP), respectively. Similarly, for every 1 °C increase in mean ambient temperature tends to 0.13 beats/min, 0.601 mmHg and 0.121 mmHg increase in HR, SBP and DBP, respectively. The measured accuracy and standard error for the HR estimation are 96%, and - 0.022 ± 2.589 beats/minute, respectively. The oxygen stauration (SpO2) measurement results shows that the mean absolute percentage error is less than 5%. The resultant errors for the SBP and DBP measurement are - 0.318 ± 5.19 mmHg and - 0.5 ± 1.91 mmHg, respectively.

Dataset Information

A New Low-Temperature Electrochemical Hydrocarbon and NOx Sensor.

Publications

A New Low-Temperature Electrochemical Hydrocarbon and NO<sub>x</sub> Sensor.

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