Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Fast ion transport through ultrathin shells of metal sulfide hollow nanocolloids used for high-performance energy storage.

ABSTRACT: Metal sulfide (MS, nickel sulfide/copper sulfide) hollow spheres with hierarchical, ultrathin shell structures have been constructed by a facile method. The as-formed MS hollow structures are shown to be uniform in sizes with hierarchical ultrathin shells, which could facilitate the transport of electrolyte ions. Electrochemical evaluations of the as-fabricated MS based materials as supercapacitors electrodes having high large surface area (106-124?m²?g^-1) and high specific capacitances (up to 1460?F?g^-1) with good cycling stability (up to 94% retention after 5000 cycles), showing their potential applications in the next-generation high-performance supercapacitors used for energy storage.

SUBMITTER: Chen Z

PROVIDER: S-EPMC5758753 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Fast ion transport through ultrathin shells of metal sulfide hollow nanocolloids used for high-performance energy storage.

Chen Zhenhua Z Zhao Mengen M Lv Xinyan X Zhou Kang K Jiang Xiaoqian X Ren Xiuli X Mei Xifan X

Scientific reports 20180108 1

Metal sulfide (MS, nickel sulfide/copper sulfide) hollow spheres with hierarchical, ultrathin shell structures have been constructed by a facile method. The as-formed MS hollow structures are shown to be uniform in sizes with hierarchical ultrathin shells, which could facilitate the transport of electrolyte ions. Electrochemical evaluations of the as-fabricated MS based materials as supercapacitors electrodes having high large surface area (106-124 m2 g-1) and high specific ...[more]

PMID: 29311670

Similar Datasets

Template-free synthesis and lithium-ion storage performance of multiple ZnO nanoparticles encapsulated in hollow amorphous carbon shells.

Project description:Due to the limited utilization of electrode materials, the rational design and facile synthesis of composite structures are still challenging issues for lithium-ion batteries (LIBs). Herein, a simple approach has been developed to prepare multiple core-shell structures of ZnO nanoparticles (NPs) encapsulated in hollow amorphous carbon (AC) shells. The as-synthesized ZnO@AC composites showed a uniform dispersion of ZnO NPs, compliant buffer AC shells, and nanoscale void spaces between the ZnO NP cores and AC shells. As a result of their structural merits, the ZnO@AC composites were evaluated as anode materials for LIBs and delivered enhanced coulombic efficiency, high reversible capacity, high rate capability, and improved cycling stability.

| S-EPMC9054705 | biostudies-literature

Preparation of Nickel Cobalt Sulfide Hollow Nanocolloids with Enhanced Electrochemical Property for Supercapacitors Application.

Project description:Nanostructured functional materials with hollow interiors are considered to be good candidates for a variety of advanced applications. However, synthesis of uniform hollow nanocolloids with porous texture via wet chemistry method is still challenging. In this work, nickel cobalt precursors (NCP) in sub-micron sized spheres have been synthesized by a facile solvothermal method. The subsequent sulfurization process in hydrothermal system has changed the NCP to nickel cobalt sulfide (NCS) with porous texture. Importantly, the hollow interiors can be tuned through the sulfurization process by employing different dosage of sulfur source. The derived NCS products have been fabricated into supercapacitor electrodes and their electrochemical performances are measured and compared, where promising results were found for the next-generation high-performance electrochemical capacitors.

| S-EPMC4844973 | biostudies-other

Hollow Gold-Silver Nanoshells Coated with Ultrathin SiO2 Shells for Plasmon-Enhanced Photocatalytic Applications.

Project description:This article details the preparation of hollow gold-silver nanoshells (GS-NSs) coated with tunably thin silica shells for use in plasmon-enhanced photocatalytic applications. Hollow GS-NSs were synthesized via the galvanic replacement of silver nanoparticles. The localized surface plasmon resonance (LSPR) peaks of the GS-NSs were tuned over the range of visible light to near-infrared (NIR) wavelengths by adjusting the ratio of silver nanoparticles to gold salt solution to obtain three distinct types of GS-NSs with LSPR peaks centered near 500, 700, and 900 nm. Varying concentrations of (3-aminopropyl)trimethoxysilane and sodium silicate solution afforded silica shell coatings of controllable thicknesses on the GS-NS cores. For each type of GS-NS, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images verified our ability to grow thin silica shells having three different thicknesses of silica shell (~2, ~10, and ~15 nm) on the GS-NS cores. Additionally, energy-dispersive X-ray (EDX) spectra confirmed the successful coating of the GS-NSs with SiO2 shells having controlled thicknesses. Extinction spectra of the as-prepared nanoparticles indicated that the silica shell has a minimal effect on the LSPR peak of the gold-silver nanoshells.

| S-EPMC7672541 | biostudies-literature

Fast Energy Storage of SnS2 Anode Nanoconfined in Hollow Porous Carbon Nanofibers for Lithium-Ion Batteries.

Project description:The development of conversion-typed anodes with ultrafast charging and large energy storage is quite challenging due to the sluggish ions/electrons transfer kinetics in bulk materials and fracture of the active materials. Herein, the design of porous carbon nanofibers/SnS2 composite (SnS2 @N-HPCNFs) for high-rate energy storage, where the ultrathin SnS2 nanosheets are nanoconfined in N-doped carbon nanofibers with tunable void spaces, is reported. The highly interconnected carbon nanofibers in three-dimensional (3D) architecture provide a fast electron transfer pathway and alleviate the volume expansion of SnS2 , while their hierarchical porous structure facilitates rapid ion diffusion. Specifically, the anode delivers a remarkable specific capacity of 1935.50 mAh g-1 at 0.1 C and excellent rate capability up to 30 C with a specific capacity of 289.60 mAh g-1 . Meanwhile, at a high rate of 20 C, the electrode displays a high capacity retention of 84% after 3000 cycles and a long cycle life of 10 000 cycles. This work provides a deep insight into the construction of electrodes with high ionic/electronic conductivity for fast-charging energy storage devices.

| S-EPMC10811495 | biostudies-literature

Robust and Fast Lithium Storage Enabled by Polypyrrole-Coated Nitrogen and Phosphorus Co-Doped Hollow Carbon Nanospheres for Lithium-Ion Capacitors.

Project description:Lithium-ion capacitors (LICs) have been proposed as an emerging technological innovation that integrates the advantages of lithium-ion batteries and supercapacitors. However, the high-power output of LICs still suffers from intractable challenges due to the sluggish reaction kinetics of battery-type anodes. Herein, polypyrrole-coated nitrogen and phosphorus co-doped hollow carbon nanospheres (NPHCS@PPy) were synthesized by a facile method and employed as anode materials for LICs. The unique hybrid architecture composed of porous hollow carbon nanospheres and PPy coating layer can expedite the mass/charge transport and enhance the structural stability during repetitive lithiation/delithiation process. The N and P dual doping plays a significant role on expanding the carbon layer spacing, enhancing electrode wettability, and increasing active sites for pseudocapacitive reactions. Benefiting from these merits, the NPHCS@PPy composite exhibits excellent lithium-storage performances including high rate capability and good cycling stability. Furthermore, a novel LIC device based on the NPHCS@PPy anode and the nitrogen-doped porous carbon cathode delivers a high energy density of 149 Wh kg-1 and a high power density of 22,500 W kg-1 as well as decent cycling stability with a capacity retention rate of 92% after 7,500 cycles. This work offers an applicable and alternative way for the development of high-performance LICs.

| S-EPMC8497749 | biostudies-literature

From Nanofibrous Hollow Microspheres to Nanofibrous Hollow Discs and Nanofibrous Shells.

Project description:Nano- and microsized structures are of central importance to advanced materials and nanotechnologies, which have tremendously impacted both biomedical and physical sciences. Herein, novel emulsification and thermally induced phase separation (TIPS) techniques to fabricate linear polymers into nanofibrous hollow objects are reported for the first time. Through manipulating the emulsification conditions, the evolution of the emulsion structure can be controlled and nanofibrous hollow microspheres with a controllable opening size and nano-fibrous shells can be fabricated. Through adjusting the rheological properties of the emulsions, nanofibrous hollow discs are also created. A new mechanistic hypotheses of the nanofibrous hollow object formation is proposed: the nano- and microscaled structures are independently determined by TIPS and the emulsification process, respectively. Guided by this theory, the nanofiber formation conditions for two further additional polymers (polyacrylonitrile and Nylon) under TIPS are identified, and solid/nanofibrous non-hollow/hollow microspheres are created from these two additional polymers under TIPS and emulsification for the first time. Therefore, the developed strategy is applicable to various polymer systems, and can broadly impact nano- and microfabrication technologies.

| S-EPMC4678097 | biostudies-literature

Entropy and Isokinetic Temperature in Fast Ion Transport.

Project description:Ion transport in crystalline solids is an essential process for many electrochemical energy converters such as solid-state batteries and fuel cells. Empirical data have shown that ion transport in crystal lattices obeys the Meyer-Neldel Rule (MNR). For similar, closely related materials, when the material properties are changed by doping or by strain, the measured ionic conductivities showing different activation energies intersect on the Arrhenius plot, at an isokinetic temperature. Therefore, the isokinetic temperature is a critical parameter for improving the ionic conductivity. However, a comprehensive understanding of the fundamental mechanism of MNR in ion transport is lacking. Here the physical significance and applicability of MNR is discussed, that is, of activation entropy-enthalpy compensation, in crystalline fast ionic conductors, and the methods for determining the isokinetic temperature. Lattice vibrations provide the excitation energy for the ions to overcome the activation barrier. The multi-excitation entropy model suggests that isokinetic temperature can be tuned by modulating the excitation phonon frequency. The relationship between isokinetic temperature and isokinetic prefactor can provide information concerning conductivity mechanisms. The need to effectively determine the isokinetic temperature for accelerating the design of new fast ionic conductors with high conductivity is highlighted.

| S-EPMC10787107 | biostudies-literature

Robust ultrathin nanoporous MOF membrane with intra-crystalline defects for fast water transport.

Project description:Rational design of high-performance stable metal-organic framework (MOF) membranes is challenging, especially for the sustainable treatment of hypersaline waters to address critical global environmental issues. Herein, a molecular-level intra-crystalline defect strategy combined with a selective layer thinning protocol is proposed to fabricate robust ultrathin missing-linker UiO-66 (ML-UiO-66) membrane to enable fast water permeation. Besides almost complete salt rejection, high and stable water flux is achieved even under long-term pervaporation operation in hash environments, which effectively addresses challenging stability issues. Then, detailed structural characterizations are employed to identify the type, chemical functionality, and density of intra-crystalline missing-linker defects. Moreover, molecular dynamics simulations shed light on the positive atomistic role of these defects, which are responsible for substantially enhancing structural hydrophilicity and enlarging pore window, consequently allowing ultra-fast water transport via a lower-energy-barrier pathway across three-dimensional sub-nanochannels during pervaporation. Unlike common unfavorable defect effects, the present positive intra-crystalline defect engineering concept at the molecular level is expected to pave a promising way toward not only rational design of next-generation MOF membranes with enhanced permeation performance, but additional water treatment applications.

| S-EPMC8752604 | biostudies-literature

Novel Mesoporous Flowerlike Iron Sulfide Hierarchitectures: Facile Synthesis and Fast Lithium Storage Capability.

Project description:The 3D flowerlike iron sulfide (F-FeS) is successfully synthesized via a facile one-step sulfurization process, and the electrochemical properties as anode materials for lithium ion batteries (LIBs) are investigated. Compared with bulk iron sulfide, we find that the unique structural features, overall flowerlike structure, composed of several dozen nanopetals and numerous small size iron sulfide particles embedded within the fine nanopetals, and hierarchical pore structure features provide signification improvements in lithium storage performance, with a high-rate discharge capacity of 779.0 mAh g-1 at a rate of 5 A g-1, due to effectively alleviating the volume expansion during the lithiation/delithiation process, and shorting the diffusion length of both lithium ion and electron. Especially, an excellent cycling stability are achieved, a high discharge capacity of 890 mAh g-1 retained at a rate of 1.0 A g-1, suggesting its promising applications in lithium ion batteries (LIBs).

| S-EPMC5746921 | biostudies-literature

Fast Na ion transport triggered by rapid ion exchange on local length scales.

Project description:The realization of green and economically friendly energy storage systems needs materials with outstanding properties. Future batteries based on Na as an abundant element take advantage of non-flammable ceramic electrolytes with very high conductivities. Na3Zr2(SiO4)2PO4-type superionic conductors are expected to pave the way for inherently safe and sustainable all-solid-state batteries. So far, only little information has been extracted from spectroscopic measurements to clarify the origins of fast ionic hopping on the atomic length scale. Here we combined broadband conductivity spectroscopy and nuclear magnetic resonance (NMR) relaxation to study Na ion dynamics from the µm to the angstrom length scale. Spin-lattice relaxation NMR revealed a very fast Na ion exchange process in Na3.4Sc0.4Zr1.6(SiO4)2PO4 that is characterized by an unprecedentedly high self-diffusion coefficient of 9 × 10-12 m2s-1 at -10 °C. Thus, well below ambient temperature the Na ions have access to elementary diffusion processes with a mean residence time τNMR of only 2 ns. The underlying asymmetric diffusion-induced NMR rate peak and the corresponding conductivity isotherms measured in the MHz range reveal correlated ionic motion. Obviously, local but extremely rapid Na+ jumps, involving especially the transition sites in Sc-NZSP, trigger long-range ion transport and push ionic conductivity up to 2 mS/cm at room temperature.

| S-EPMC6086902 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data