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Template-free synthesis and lithium-ion storage performance of multiple ZnO nanoparticles encapsulated in hollow amorphous carbon shells.


ABSTRACT: Due to the limited utilization of electrode materials, the rational design and facile synthesis of composite structures are still challenging issues for lithium-ion batteries (LIBs). Herein, a simple approach has been developed to prepare multiple core-shell structures of ZnO nanoparticles (NPs) encapsulated in hollow amorphous carbon (AC) shells. The as-synthesized ZnO@AC composites showed a uniform dispersion of ZnO NPs, compliant buffer AC shells, and nanoscale void spaces between the ZnO NP cores and AC shells. As a result of their structural merits, the ZnO@AC composites were evaluated as anode materials for LIBs and delivered enhanced coulombic efficiency, high reversible capacity, high rate capability, and improved cycling stability.

SUBMITTER: Jin Y 

PROVIDER: S-EPMC9054705 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature

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Template-free synthesis and lithium-ion storage performance of multiple ZnO nanoparticles encapsulated in hollow amorphous carbon shells.

Jin Yunxia Y   Wang Shimin S   Li Jia J   Qu Sheng S   Yang Liufang L   Guo Junming J  

RSC advances 20200615 38


Due to the limited utilization of electrode materials, the rational design and facile synthesis of composite structures are still challenging issues for lithium-ion batteries (LIBs). Herein, a simple approach has been developed to prepare multiple core-shell structures of ZnO nanoparticles (NPs) encapsulated in hollow amorphous carbon (AC) shells. The as-synthesized ZnO@AC composites showed a uniform dispersion of ZnO NPs, compliant buffer AC shells, and nanoscale void spaces between the ZnO NP  ...[more]

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