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Magnesium, zinc, aluminium and gallium hydride complexes of the transition metals.

ABSTRACT: The preparation and applications of heterobimetallic complexes continue to occupy researchers in the fields of organometallic, main group, and coordination chemistry. This interest stems from the promise these complexes hold as precursors to materials, reagents in synthesis and as new catalysis. Here we survey and organise the state-of-the-art understanding of the TM-H-M linkage (M = Mg, Zn, Al, Ga). We discuss the structure and bonding in these complexes, their known reactivity, and their largely unrealised potential in catalysis.

SUBMITTER: Butler MJ

PROVIDER: S-EPMC5777540 | biostudies-literature | 2017 Jan

REPOSITORIES: biostudies-literature

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Magnesium, zinc, aluminium and gallium hydride complexes of the transition metals.

Butler Michael J MJ Crimmin Mark R MR

Chemical communications (Cambridge, England) 20170101 8

The preparation and applications of heterobimetallic complexes continue to occupy researchers in the fields of organometallic, main group, and coordination chemistry. This interest stems from the promise these complexes hold as precursors to materials, reagents in synthesis and as new catalysis. Here we survey and organise the state-of-the-art understanding of the TM-H-M linkage (M = Mg, Zn, Al, Ga). We discuss the structure and bonding in these complexes, their known reactivity, and their large ...[more]

PMID: 28070586

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Dataset Information

Magnesium, zinc, aluminium and gallium hydride complexes of the transition metals.

Publications

Magnesium, zinc, aluminium and gallium hydride complexes of the transition metals.

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