Ontology highlight
ABSTRACT:
SUBMITTER: Sandfort F
PROVIDER: S-EPMC5792188 | biostudies-literature | 2017 Mar
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20170210 12
Suzuki, Negishi, and Kumada couplings are some of the most important reactions for the formation of skeletal C-C linkages. Their widespread use to forge bonds between two aromatic rings has enabled every branch of chemical science. The analogous union between alkyl halides and metallated aryl systems has not been as widely employed due to the lack of commercially available halide building blocks. Redox-active esters have recently emerged as useful surrogates for alkyl halides in cross-coupling c ...[more]