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Alkyl Aryl Ether Bond Formation with PhenoFluor.


ABSTRACT: An alkyl aryl ether bond formation reaction between phenols and primary and secondary alcohols with PhenoFluor has been developed. The reaction features a broad substrate scope and tolerates many functional groups, and substrates that are challenging for more conventional ether bond forming processes may be coupled. A preliminary mechanistic study indicates reactivity distinct from conventional ether bond formation.

SUBMITTER: Shen X 

PROVIDER: S-EPMC4487836 | biostudies-literature | 2015 May

REPOSITORIES: biostudies-literature

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Alkyl Aryl Ether Bond Formation with PhenoFluor.

Shen Xiao X   Neumann Constanze N CN   Kleinlein Claudia C   Goldberg Nathaniel W NW   Ritter Tobias T  

Angewandte Chemie (International ed. in English) 20150320 19


An alkyl aryl ether bond formation reaction between phenols and primary and secondary alcohols with PhenoFluor has been developed. The reaction features a broad substrate scope and tolerates many functional groups, and substrates that are challenging for more conventional ether bond forming processes may be coupled. A preliminary mechanistic study indicates reactivity distinct from conventional ether bond formation. ...[more]

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