Ontology highlight
ABSTRACT:
SUBMITTER: Carlson MR
PROVIDER: S-EPMC5821139 | biostudies-literature | 2018 Feb
REPOSITORIES: biostudies-literature
Carlson Michaela R MR Gray Danielle L DL Richers Casseday P CP Wang Wenguang W Zhao Pei-Hua PH Rauchfuss Thomas B TB Pelmenschikov Vladimir V Pham Cindy C CC Gee Leland B LB Wang Hongxin H Cramer Stephen P SP
Inorganic chemistry 20180131 4
The kinetically robust hydride [t-HFe<sub>2</sub>(Me<sub>2</sub>pdt)(CO)<sub>2</sub>(dppv)<sub>2</sub>]<sup>+</sup> ([t-H1]<sup>+</sup>) (Me<sub>2</sub>pdt<sup>2-</sup> = Me<sub>2</sub>C(CH<sub>2</sub>S<sup>-</sup>)<sub>2</sub>; dppv = cis-1,2-C<sub>2</sub>H<sub>2</sub>(PPh<sub>2</sub>)<sub>2</sub>) and related derivatives were prepared with <sup>57</sup>Fe enrichment for characterization by NMR, FT-IR, and NRVS. The experimental results were rationalized using DFT molecular modeling and spectra ...[more]