Ontology highlight
ABSTRACT:
SUBMITTER: Sorochkina K
PROVIDER: S-EPMC5862329 | biostudies-literature | 2018 Feb
REPOSITORIES: biostudies-literature
The journal of physical chemistry letters 20180208 4
The ability of frustrated Lewis pairs (FLPs) to activate H<sub>2</sub> is of significant interest for metal-free catalysis. The activation of H<sub>2</sub> is also the key element of parahydrogen-induced polarization (PHIP), one of the nuclear spin hyperpolarization techniques. It is demonstrated that o-phenylene-based ansa-aminoboranes (AABs) can produce <sup>1</sup>H nuclear spin hyperpolarization through a reversible interaction with parahydrogen at ambient temperatures. Heteronuclei are usef ...[more]