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Colorimetric detection of hydrogen peroxide by dioxido-vanadium(V) complex containing hydrazone ligand: synthesis and crystal structure.

ABSTRACT: Dioxido-vanadium(V) complex has been synthesized in good yield, the complex was characterized by IR, UV-visible and 1H NMR spectroscopy. Single crystal X-ray crystallography techniques were used to assign the structure of the complex. Complex crystallized with monoclinic P21/c space group with cell parameters a (Å)?=?39.516(5), b (Å)?=?6.2571(11), c (Å)?=?17.424(2), ? (°)?=?90, ? (°)?=?102.668(12) and ? (°)?=?90. The hydrazone ligand is coordinate to metal ion in tridentate fashion through -ONO- donor atoms forming a distorted square pyramidal geometry around the metal ion.

SUBMITTER: Kurbah SD

PROVIDER: S-EPMC5882683 | biostudies-literature | 2018 Mar

REPOSITORIES: biostudies-literature

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Colorimetric detection of hydrogen peroxide by dioxido-vanadium(V) complex containing hydrazone ligand: synthesis and crystal structure.

Kurbah Sunshine D SD Syiemlieh Ibanphylla I Lal Ram A RA

Royal Society open science 20180314 3

Dioxido-vanadium(V) complex has been synthesized in good yield, the complex was characterized by IR, UV-visible and 1H NMR spectroscopy. Single crystal X-ray crystallography techniques were used to assign the structure of the complex. Complex crystallized with monoclinic P21/c space group with cell parameters a (Å) = 39.516(5), b (Å) = 6.2571(11), c (Å) = 17.424(2), α (°) = 90, β (°) = 102.668(12) and γ (°) = 90. The h ...[more]

PMID: 29657759

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