Ontology highlight
ABSTRACT:
SUBMITTER: Norell J
PROVIDER: S-EPMC5885270 | biostudies-literature | 2018 Mar
REPOSITORIES: biostudies-literature
Norell Jesper J Jay Raphael M RM Hantschmann Markus M Eckert Sebastian S Guo Meiyuan M Gaffney Kelly J KJ Wernet Philippe P Lundberg Marcus M Föhlisch Alexander A Odelius Michael M
Physical chemistry chemical physics : PCCP 20180301 10
We describe how inversion symmetry separation of electronic state manifolds in resonant inelastic soft X-ray scattering (RIXS) can be applied to probe excited-state dynamics with compelling selectivity. In a case study of Fe L<sub>3</sub>-edge RIXS in the ferricyanide complex Fe(CN)<sub>6</sub><sup>3-</sup>, we demonstrate with multi-configurational restricted active space spectrum simulations how the information content of RIXS spectral fingerprints can be used to unambiguously separate species ...[more]