Ontology highlight
ABSTRACT:
SUBMITTER: Hu X
PROVIDER: S-EPMC5887105 | biostudies-literature | 2018 Feb
REPOSITORIES: biostudies-literature
Hu Xia X Zhang Guoting G Bu Faxiang F Luo Xu X Yi Kebing K Zhang Heng H Lei Aiwen A
Chemical science 20171208 6
The dehydrogenative cross-coupling of arenes and alkenes is a particularly ideal approach for the synthesis of aryl alkenes. Herein, we report a photo-induced C-H/C-H cross-coupling between electron-rich arenes and styrene derivatives using a dual catalytic system containing an acridinium photosensitizer and a cobaloxime proton-reducing catalyst. This catalytic system enables the Csp<sup>2</sup>-Csp<sup>2</sup> bond formation accompanying H<sub>2</sub> evolution. Various substituted aryl alkenes ...[more]