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A high-strength silicide phase in a stainless steel alloy designed for wear-resistant applications.

ABSTRACT: Hardfacing alloys provide strong, wear-resistant and corrosion-resistant coatings for extreme environments such as those within nuclear reactors. Here, we report an ultra-high-strength Fe-Cr-Ni silicide phase, named ?-ferrosilicide, within a hardfacing Fe-based alloy. Electron diffraction tomography has allowed the determination of the atomic structure of this phase. Nanohardness testing indicates that the ?-ferrosilicide phase is up to 2.5 times harder than the surrounding austenite and ferrite phases. The compressive strength of the ?-ferrosilicide phase is exceptionally high and does not yield despite loading in excess of 1.6?GPa. Such a high-strength silicide phase could not only provide a new type of strong, wear-resistant and corrosion-resistant Fe-based coating, replacing more costly and hazardous Co-based alloys for nuclear applications, but also lead to the development of a new class of high-performance silicide-strengthened stainless steels, no longer reliant on carbon for strengthening.

SUBMITTER: Bowden D

PROVIDER: S-EPMC5893616 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Wear resistance of an additively manufactured high-carbon martensitic stainless steel.

Project description:The dry sliding wear behaviour of a high carbon martensitic stainless steel (HCMSS) consisting of ~ 22.5 vol% of chromium (Cr)- and vanadium (V)-rich carbides processed by electron beam melting (EBM) has been captured. The microstructure consisted of martensite and retained austenite phases with a homogeneous distribution of sub-micron-sized V-rich and micron-sized Cr-rich carbides, leading to relatively high hardness. The CoF decreased ~ 14.1% with increasing load in the steady-state, due to the material transferred from the wear track over the counterbody. The wear rate of the HCMSS compared to martensitic tool steel processed in the same manner, and it was nearly identical under low applied load. The dominant wear mechanism was removal of the steel matrix through abrasion, followed by the oxidation of the wear track, while three-body abrasive wear occurred with increasing load. A plastically deformed zone beneath the wear track was revealed through cross-sectional hardness mapping. Specific phenomena occurred with increasingly aggressive wear conditions were described with carbide cracking, pull-out of V-rich carbides and matrix cracking. This study revealed the wear performance of the additively manufactured HCMSS, which could pave the way for producing components for wear-related applications ranging from shafts to plastic injection moulds via EBM.

| S-EPMC9307504 | biostudies-literature

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| S-EPMC4295098 | biostudies-literature

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2010-04-30 | GSE20174 | GEO

Alloy and composition dependence of hydrogen embrittlement susceptibility in high-strength steel fasteners.

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Gradient Microstructure Design in Stainless Steel: A Strategy for Uniting Strength-Ductility Synergy and Corrosion Resistance.

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| S-EPMC8472316 | biostudies-literature

Towards development of a high-strength stainless Mg alloy with Al-assisted growth of passive film

Project description:Magnesium alloys with high strength and excellent corrosion resistance are always sought-after in light-weighting structural components for automotive and aerospace applications. However, for most magnesium alloys that have a high specific strength, they usually have an inferior corrosion resistance and vice versa. In this work, we successfully develop a Mg-11Y-1Al (wt. %) alloy through conventional casting, solution treatment followed by extrusion. The overall properties of this alloy feature with a corrosion rate lower than 0.2 mm y−1, high yield strength of 350 MPa and moderate tensile elongation of 8%, the combination of which shows competitive advantage over other comparative magnesium alloys in the literature. It is found that a thin and dense protective film of Y2O3/Y(OH)3 can be fast developed with the aid of Al2O3/Al(OH)3 deposition to isolate this alloy from further attack of corrosion medium. Meanwhile, the refined grains, weak texture and activation of non-basal slip systems co-contribute to the high strength and good ductility. Our findings are expected to inspire the design of next-generation high performance magnesium alloys. High-strength Mg alloys are often sought-after for automotive and aerospace applications, but they have an inferior corrosion resistance. Here, the authors develop a Mg-11Y-1Al (wt. %) alloy that shows both significantly improved mechanical properties and corrosion resistance.

| S-EPMC9529920 | biostudies-literature

Microstructure and Mechanical Properties of Butt Joints between Stainless Steel SUS304L and Aluminum Alloy A6061-T6 by TIG Welding.

Project description:The tungsten inert gas (TIG) welding method most commonly used to weld ferrous metals, nonferrous metals, and other metals since it is simple, easily implemented, and achieves consistent high-quality welds. In this study, butt joints produced between aluminum alloy A6061-T6 and stainless steel SUS304L have been achieved by using TIG welding with ER4047 filler metal. The macrostructure and microstructure of the resulting specimens were analyzed by means of an optical microscope (OM), a scanning electron microscope (SEM), and an energy dispersive X-ray spectrometer (EDS). A uniform intermetallic layer was found at the interface between the stainless steel and the weld seam having a thickness of 2 µm, and the intermetallic compound (IMC) includes Fe?Al13, Fe?Al?, and FeAl? phases. The micro-hardness and tensile strength of the weld joints were also investigated. Due to Si content in the compensating metal, there was a prevention of iron diffusion into the aluminum, thus hindering the development of the IMC layer and reducing its thickness in such a way that the weld joint strength increases. The analyzed results show that the average micro-hardness of the stainless steel, weld seam, aluminum alloys, and IMC layer were 218 HV, 88.3 HV, 63.3 HV, and 411 HV, respectively. The fracture occurred at the brazed interface, and the ultimate tensile strength value reached 225 MPa.

| S-EPMC6073269 | biostudies-literature

Osteoblast Biocompatibility and Antibacterial Effects Using 2-Methacryloyloxyethyl Phosphocholine-Grafted Stainless-Steel Composite for Implant Applications.

Project description:Poor osteogenesis and bacterial infections lead to an implant failure, so the enhanced osteogenic and antimicrobial activity of the implantable device is of great importance in orthopedic applications. In this study, 2-methacryloyloxyethyl phosphocholine (MPC) was grafted onto 316L stainless steel (SS) using a facile photo-induced radical graft polymerization method via a benzophenone (BP) photo initiator. Atomic force microscopy (AFM) was employed to determine the nanoscale morphological changes on the surface. The grafted BP-MPC layer was estimated to be tens of nanometers thick. The SS-BP-MPC composite was more hydrophilic and smoother than the untreated and BP-treated SS samples. Staphylococcus aureus (S. aureus) bacteria binding onto the SS-BP-MPC composite film surface was significantly reduced compared with the pristine SS and SS-BP samples. Mouse pre-osteoblast (MC3T3-E1) cells showed good adhesion on the MPC-modified samples and better proliferation and metabolic activity (73% higher) than the pristine SS sample. Biological studies revealed that grafting MPC onto the SS substrate enhanced the antibacterial efficiency and also retained osteoblast biocompatibility. This proposed procedure is promising for use with other implant materials.

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Stacking Fault Energy Analyses of Additively Manufactured Stainless Steel 316L and CrCoNi Medium Entropy Alloy Using In Situ Neutron Diffraction.

Project description:Stacking fault energies (SFE) were determined in additively manufactured (AM) stainless steel (SS 316 L) and equiatomic CrCoNi medium-entropy alloys. AM specimens were fabricated via directed energy deposition and tensile loaded at room temperature. In situ neutron diffraction was performed to obtain a number of faulting-embedded diffraction peaks simultaneously from a set of (hkl) grains during deformation. The peak profiles diffracted from imperfect crystal structures were analyzed to correlate stacking fault probabilities and mean-square lattice strains to the SFE. The result shows that averaged SFEs are 32.8 mJ/m2 for the AM SS 316 L and 15.1 mJ/m2 for the AM CrCoNi alloys. Meanwhile, during deformation, the SFE varies from 46 to 21 mJ/m2 (AM SS 316 L) and 24 to 11 mJ/m2 (AM CrCoNi) from initial to stabilized stages, respectively. The transient SFEs are attributed to the deformation activity changes from dislocation slip to twinning as straining. The twinning deformation substructure and atomic stacking faults were confirmed by electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). The significant variance of the SFE suggests the critical twinning stress as 830 ± 25 MPa for the AM SS 316 L and 790 ± 40 MPa for AM CrCoNi, respectively.

| S-EPMC6987211 | biostudies-literature

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