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A high-strength silicide phase in a stainless steel alloy designed for wear-resistant applications.


ABSTRACT: Hardfacing alloys provide strong, wear-resistant and corrosion-resistant coatings for extreme environments such as those within nuclear reactors. Here, we report an ultra-high-strength Fe-Cr-Ni silicide phase, named ?-ferrosilicide, within a hardfacing Fe-based alloy. Electron diffraction tomography has allowed the determination of the atomic structure of this phase. Nanohardness testing indicates that the ?-ferrosilicide phase is up to 2.5 times harder than the surrounding austenite and ferrite phases. The compressive strength of the ?-ferrosilicide phase is exceptionally high and does not yield despite loading in excess of 1.6?GPa. Such a high-strength silicide phase could not only provide a new type of strong, wear-resistant and corrosion-resistant Fe-based coating, replacing more costly and hazardous Co-based alloys for nuclear applications, but also lead to the development of a new class of high-performance silicide-strengthened stainless steels, no longer reliant on carbon for strengthening.

SUBMITTER: Bowden D 

PROVIDER: S-EPMC5893616 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature

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A high-strength silicide phase in a stainless steel alloy designed for wear-resistant applications.

Bowden D D   Krysiak Y Y   Palatinus L L   Tsivoulas D D   Plana-Ruiz S S   Sarakinou E E   Kolb U U   Stewart D D   Preuss M M  

Nature communications 20180410 1


Hardfacing alloys provide strong, wear-resistant and corrosion-resistant coatings for extreme environments such as those within nuclear reactors. Here, we report an ultra-high-strength Fe-Cr-Ni silicide phase, named π-ferrosilicide, within a hardfacing Fe-based alloy. Electron diffraction tomography has allowed the determination of the atomic structure of this phase. Nanohardness testing indicates that the π-ferrosilicide phase is up to 2.5 times harder than the surrounding austenite and ferrite  ...[more]

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