Ontology highlight
ABSTRACT:
SUBMITTER: Zhang HJ
PROVIDER: S-EPMC5927363 | biostudies-literature | 2018 Apr
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20180409 15
A mild and operationally simple copper-catalyzed vinylogous aerobic oxidation of β,γ- and α,β-unsaturated esters is described. This method features good yields, broad substrate scope, excellent chemo- and regioselectivity, and good functional group tolerance. This method is additionally capable of oxidizing β,γ- and α,β-unsaturated aldehydes, ketones, amides, nitriles, and sulfones. Furthermore, the present catalytic system is suitable for bisvinylogous and trisvinylogous oxidation. Tetramethylg ...[more]