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Heterogeneous local order in self-assembled nanoparticle films revealed by X-ray cross-correlations.

ABSTRACT: We report on the self-assembly of gold nanoparticles coated with a soft poly(ethylene glycol) shell studied by X-ray cross-correlation analysis. Depending on the initial concentration of gold nanoparticles used, structurally heterogeneous films were formed. The films feature hot spots of dominating four- and sixfold local order with patch sizes of a few micrometres, containing 104-105 particles. The amplitude of the order parameters suggested that a minimum sample amount was necessary to form well ordered local structures. Furthermore, the increasing variation in order parameters with sample thickness demonstrated a high degree of structural heterogeneity. This wealth of information cannot be obtained by the conventional microscopy techniques that are commonly used to study nanocrystal superstructures, as illustrated by complementary scanning electron microscopy measurements.

SUBMITTER: Lehmkuhler F

PROVIDER: S-EPMC5929381 | biostudies-literature | 2018 May

REPOSITORIES: biostudies-literature

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Heterogeneous local order in self-assembled nanoparticle films revealed by X-ray cross-correlations.

Lehmkühler Felix F Schulz Florian F Schroer Martin A MA Frenzel Lara L Lange Holger H Grübel Gerhard G

IUCrJ 20180428 Pt 3

We report on the self-assembly of gold nanoparticles coated with a soft poly(ethylene glycol) shell studied by X-ray cross-correlation analysis. Depending on the initial concentration of gold nanoparticles used, structurally heterogeneous films were formed. The films feature hot spots of dominating four- and sixfold local order with patch sizes of a few micrometres, containing 10<sup>4</sup>-10<sup>5</sup> particles. The amplitude of the order parameters suggested that a minimum sample amount wa ...[more]

PMID: 29755751

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