Ontology highlight
ABSTRACT:
SUBMITTER: Franco F
PROVIDER: S-EPMC5947128 | biostudies-literature | 2018 Apr
REPOSITORIES: biostudies-literature
Franco Federico F Pinto Mara F MF Royo Beatriz B Lloret-Fillol Julio J
Angewandte Chemie (International ed. in English) 20180314 17
We report here the first purely organometallic fac-[Mn<sup>I</sup> (CO)<sub>3</sub> (bis-<sup>Me</sup> NHC)Br] complex with unprecedented activity for the selective electrocatalytic reduction of CO<sub>2</sub> to CO, exceeding 100 turnovers with excellent faradaic yields (η<sub>CO</sub> ≈95 %) in anhydrous CH<sub>3</sub> CN. Under the same conditions, a maximum turnover frequency (TOF<sub>max</sub> ) of 2100 s<sup>-1</sup> was measured by cyclic voltammetry, which clearly exceeds the values repo ...[more]