Ontology highlight
ABSTRACT:
SUBMITTER: McKinnon M
PROVIDER: S-EPMC6771302 | biostudies-literature | 2019
REPOSITORIES: biostudies-literature
McKinnon Meaghan M Belkina Veronika V Ngo Ken T KT Ertem Mehmed Z MZ Grills David C DC Rochford Jonathan J
Frontiers in chemistry 20190924
The subject of this study [<i>fac</i>-Mn(bqn)(CO)<sub>3</sub>(CH<sub>3</sub>CN)]<sup>+</sup> (bqn = 2,2'-biquinoline), is of particular interest because the bqn ligand exhibits both steric and electronic influence over the fundamental redox properties of the complex and, consequently, its related catalytic properties with respect to the activation of CO<sub>2</sub>. While not a particularly efficient catalyst for CO<sub>2</sub> to CO conversion, <i>in-situ</i> generation and activity measurement ...[more]