Browse
Submit Data
Databases
API
Help

Dataset Information

25 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Emergent superconductivity in an iron-based honeycomb lattice initiated by pressure-driven spin-crossover.

ABSTRACT: The discovery of iron-based superconductors (FeSCs), with the highest transition temperature (Tc) up to 55 K, has attracted worldwide research efforts over the past ten years. So far, all these FeSCs structurally adopt FeSe-type layers with a square iron lattice and superconductivity can be generated by either chemical doping or external pressure. Herein, we report the observation of superconductivity in an iron-based honeycomb lattice via pressure-driven spin-crossover. Under compression, the layered FePX3 (X = S, Se) simultaneously undergo large in-plane lattice collapses, abrupt spin-crossovers, and insulator-metal transitions. Superconductivity emerges in FePSe3 along with the structural transition and vanishing of magnetic moment with a starting Tc ~ 2.5 K at 9.0 GPa and the maximum Tc ~ 5.5 K around 30 GPa. The discovery of superconductivity in iron-based honeycomb lattice provides a demonstration for the pursuit of transition-metal-based superconductors via pressure-driven spin-crossover.

SUBMITTER: Wang Y

PROVIDER: S-EPMC5953925 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Randomness-induced quantum spin liquid on honeycomb lattice.

Project description:Quantum entanglement in magnetic materials is expected to yield a quantum spin liquid (QSL), in which strong quantum fluctuations prevent magnetic ordering even at zero temperature. This topic has been one of the primary focuses of condensed-matter science since Anderson first proposed the resonating valence bond state in a certain spin-1/2 frustrated magnet in 1973. Since then, several candidate materials featuring frustration, such as triangular and kagome lattices, have been reported to exhibit liquid-like behavior. However, the mechanisms that stabilize the liquid-like states have remained elusive. Here, we present a QSL state in a spin-1/2 honeycomb lattice with randomness in the exchange interaction. That is, we successfully introduce randomness into the organic radial-based complex and realize a random-singlet (RS) state (or valence bond glass). All magnetic and thermodynamic experimental results indicate the liquid-like behaviors, which are consistent with those expected in the RS state. Our results suggest that the randomness or inhomogeneity in the actual systems stabilize the RS state and yield liquid-like behavior.

| S-EPMC5701036 | biostudies-literature

Quantum loop states in spin-orbital models on the honeycomb lattice.

Project description:The search for truly quantum phases of matter is a center piece of modern research in condensed matter physics. Quantum spin liquids, which host large amounts of entanglement-an entirely quantum feature where one part of a system cannot be measured without modifying the rest-are exemplars of such phases. Here, we devise a realistic model which relies upon the well-known Haldane chain phase, i.e. the phase of spin-1 chains which host fractional excitations at their ends, akin to the hallmark excitations of quantum spin liquids. We tune our model to exactly soluble points, and find that the ground state realizes Haldane chains whose physical supports fluctuate, realizing both quantum spin liquid like and symmetry-protected topological phases. Crucially, this model is expected to describe actual materials, and we provide a detailed set of material-specific constraints which may be readily used for an experimental realization.

| S-EPMC8139991 | biostudies-literature

Learning spin liquids on a honeycomb lattice with artificial neural networks.

Project description:Machine learning methods provide a new perspective on the study of many-body system in condensed matter physics and there is only limited understanding of their representational properties and limitations in quantum spin liquid systems. In this work, we investigate the ability of the machine learning method based on the restricted Boltzmann machine in capturing physical quantities including the ground-state energy, spin-structure factor, magnetization, quantum coherence, and multipartite entanglement in the two-dimensional ferromagnetic spin liquids on a honeycomb lattice. It is found that the restricted Boltzmann machine can encode the many-body wavefunction quite well by reproducing accurate ground-state energy and structure factor. Further investigation on the behavior of multipartite entanglement indicates that the residual entanglement is richer in the gapless phase than the gapped spin-liquid phase, which suggests that the residual entanglement can characterize the spin-liquid phases. Additionally, we confirm the existence of a gapped non-Abelian topological phase in the spin liquids on a honeycomb lattice with a small magnetic field and determine the corresponding phase boundary by recognizing the rapid change of the local magnetization and residual entanglement.

| S-EPMC8371168 | biostudies-literature

Pressure-Driven Spin Crossover Involving Polyhedral Transformation in Layered Perovskite Cobalt Oxyfluoride.

Project description:We report a novel pressure-driven spin crossover in layered cobalt oxyfluoride Sr2CoO3F with a distorted CoO5 square pyramid loosely bound with a fluoride ion. Upon increasing pressure, the spin state of the Co(III) cation gradually changes from a high spin state (S?=?2) to a low spin state (S?=?0) accompanied by a anomalously large volume contraction (bulk modulus, 76.8(5) GPa). The spin state change occurs on the CoO5 pyramid in a wide pressure range, but the concomitant gradual shrinkage of the Co-F bond length with pressure gives rise to a polyhedral transformation to the CoO5F octahedron without a structural phase transition, leading to the full conversion to the LS state at 12?GPa. The present results provide new effective strategy to fine-tune electronic properties of mixed anion systems by controlling the covalency in metal-ligand bonds under pressure.

| S-EPMC5090247 | biostudies-literature

Strongly frustrated triangular spin lattice emerging from triplet dimer formation in honeycomb Li2IrO3.

Project description:Iridium oxides with a honeycomb lattice have been identified as platforms for the much anticipated Kitaev topological spin liquid: the spin-orbit entangled states of Ir(4+) in principle generate precisely the required type of anisotropic exchange. However, other magnetic couplings can drive the system away from the spin-liquid phase. With this in mind, here we disentangle the different magnetic interactions in Li2IrO3, a honeycomb iridate with two crystallographically inequivalent sets of adjacent Ir sites. Our ab initio many-body calculations show that, while both Heisenberg and Kitaev nearest-neighbour couplings are present, on one set of Ir-Ir bonds the former dominates, resulting in the formation of spin-triplet dimers. The triplet dimers frame a strongly frustrated triangular lattice and by exact cluster diagonalization we show that they remain protected in a wide region of the phase diagram.

| S-EPMC4735606 | biostudies-literature

Two-Dimensional Pnictogen Honeycomb Lattice: Structure, On-Site Spin-Orbit Coupling and Spin Polarization.

Project description:Because of its novel physical properties, two-dimensional materials have attracted great attention. From first-principle calculations and vibration frequencies analysis, we predict a new family of two-dimensional materials based on the idea of octet stability: honeycomb lattices of pnictogens (N, P, As, Sb, Bi). The buckled structures of materials come from the sp(3) hybridization. These materials have indirect band gap ranging from 0.43 eV to 3.7 eV. From the analysis of projected density of states, we argue that the s and p orbitals together are sufficient to describe the electronic structure under tight-binding model, and the tight-binding parameters are obtained by fitting the band structures to first-principle results. Surprisingly large on-site spin-orbit coupling is found for all the pnictogen lattices except nitrogen. Investigation on the electronic structures of both zigzag and armchair nanoribbons reveals the possible existence of spin-polarized ferromagnetic edge states in some cases, which are rare in one-dimensional systems. These edge states and magnetism may exist under the condition of high vacuum and low temperature. This new family of materials would have promising applications in electronics, optics, sensors, and solar cells.

| S-EPMC4485072 | biostudies-other

Spin Solid versus Magnetic Charge Ordered State in Artificial Honeycomb Lattice of Connected Elements.

Project description:The nature of magnetic correlation at low temperature in two-dimensional artificial magnetic honeycomb lattice is a strongly debated issue. While theoretical researches suggest that the system will develop a novel zero entropy spin solid state as T ? 0 K, a confirmation to this effect in artificial honeycomb lattice of connected elements is lacking. This study reports on the investigation of magnetic correlation in newly designed artificial permalloy honeycomb lattice of ultrasmall elements, with a typical length of ?12 nm, using neutron scattering measurements and temperature-dependent micromagnetic simulations. Numerical modeling of the polarized neutron reflectometry data elucidates the temperature-dependent evolution of spin correlation in this system. As temperature reduces to ?7 K, the system tends to develop novel spin solid state, manifested by the alternating distribution of magnetic vortex loops of opposite chiralities. Experimental results are complemented by temperature-dependent micromagnetic simulations that confirm the dominance of spin solid state over local magnetic charge ordered state in the artificial honeycomb lattice with connected elements. These results enable a direct investigation of novel spin solid correlation in the connected honeycomb geometry of 2D artificial structure.

| S-EPMC5908362 | biostudies-literature

Absence of a spin liquid phase in the Hubbard model on the honeycomb lattice.

Project description:A spin liquid is a novel quantum state of matter with no conventional order parameter where a finite charge gap exists even though the band theory would predict metallic behavior. Finding a stable spin liquid in two or higher spatial dimensions is one of the most challenging and debated issues in condensed matter physics. Very recently, it has been reported that a model of graphene, i.e., the Hubbard model on the honeycomb lattice, can show a spin liquid ground state in a wide region of the phase diagram, between a semi-metal (SM) and an antiferromagnetic insulator (AFMI). Here, by performing numerically exact quantum Monte Carlo simulations, we extend the previous study to much larger clusters (containing up to 2592 sites), and find, if any, a very weak evidence of this spin liquid region. Instead, our calculations strongly indicate a direct and continuous quantum phase transition between SM and AFMI.

| S-EPMC3524549 | biostudies-literature

Candidate quantum spin liquid due to dimensional reduction of a two-dimensional honeycomb lattice.

Project description:As with quantum spin liquids based on two-dimensional triangular and kagome lattices, the two-dimensional honeycomb lattice with either a strong spin-orbital coupling or a frustrating second-nearest-neighbor coupling is expected to be a source of candidate quantum spin liquids. An ammonium salt [(C3H7)3NH]2[Cu2(C2O4)3](H2O)2.2 containing hexagonal layers of Cu(2+) was obtained from solution. No structural transition or long-range magnetic ordering was observed from 290 K to 2 K from single crystal X-ray diffraction, specific heat and susceptibility measurements. The anionic layers are separated by sheets of ammonium and H2O with distance of 3.5 Å and no significant interaction between anionic layers. The two-dimensional honeycomb lattice is constructed from Jahn-Teller distorted Cu(2+) and oxalate anions, showing a strong antiferromagnetic interaction between S = 1/2 metal atoms with θ = -120 (1) K. Orbital analysis of the Cu(2+) interactions through the oxalate-bridges suggests a stripe mode pattern of coupling with weak ferromagnetic interaction along the b axis, and strong antiferromagnetic interaction along the a axis. Analysis of the magnetic susceptibility shows that it is dominated by a quasi-one-dimensional contribution with spin chains that are at least as well isolated as those of well-known quasi-one-dimensional spin liquids.

| S-EPMC5377320 | biostudies-literature

Iron(II) Spin Crossover Complexes with 4,4'-Dipyridylethyne-Crystal Structures and Spin Crossover with Hysteresis.

Project description:Three new iron(II) 1D coordination polymers with cooperative spin crossover behavior showing thermal hysteresis loops were synthesized using N2O2 Schiff base-like equatorial ligands and 4,4'-dipyridylethyne as a bridging, rigid axial linker. One of those iron(II) 1D coordination polymers showed a 73 K wide hysteresis below room temperature, which, upon solvent loss, decreased to a still remarkable 30 K wide hysteresis. Single crystal X-ray structures of two iron(II) coordination polymers and T-dependent powder XRD patterns are discussed to obtain insight into the structure property relationship of those materials.

| S-EPMC7037042 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data