Ontology highlight
ABSTRACT:
SUBMITTER: Krause SB
PROVIDER: S-EPMC5983356 | biostudies-literature | 2017 Oct
REPOSITORIES: biostudies-literature
Organic letters 20170929 20
Studies of the silyl-Heck reaction aimed at identifying active palladium complexes have revealed a new species that is formed in situ. This complex has been identified as the palladium iodide dimer, [(JessePhos)PdI<sub>2</sub>]<sub>2</sub>, which has been found to be a competent single-component precatalyst for the silyl-Heck reaction. This complex is easily prepared and is temperature, moisture, and air stable. Additionally, this precatalyst provides higher activity and greater reproducibility ...[more]