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Rechargeable aluminum-selenium batteries with high capacity.

ABSTRACT: Rechargeable aluminum (Al) batteries are emerging as a promising post lithium-ion battery technology. Herein, we demonstrate a conceptually new design of rechargeable aluminum-selenium (Al-Se) batteries by understanding the selenium chemistry and controlling the electrode reaction. The Al-Se battery consists of a composite cathode including selenium nanowires and mesoporous carbon (CMK-3) nanorods, an Al metal anode and chloroaluminate ionic liquid electrolyte. The working mechanism of the Al-Se battery is the reversible redox reaction of the Se2Cl2/Se pair confined in the mesopores of CMK-3 nanorods. Al-Se batteries deliver a high reversible capacity of 178 mA h g-1 (by Se mass), high discharge voltages (mainly above 1.5 V), and good cycling/rate performances.

SUBMITTER: Huang X

PROVIDER: S-EPMC6001279 | biostudies-literature | 2018 Jun

REPOSITORIES: biostudies-literature

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Rechargeable aluminum-selenium batteries with high capacity.

Huang Xiaodan X Liu Yang Y Liu Chao C Zhang Jun J Noonan Owen O Yu Chengzhong C

Chemical science 20180517 23

Rechargeable aluminum (Al) batteries are emerging as a promising post lithium-ion battery technology. Herein, we demonstrate a conceptually new design of rechargeable aluminum-selenium (Al-Se) batteries by understanding the selenium chemistry and controlling the electrode reaction. The Al-Se battery consists of a composite cathode including selenium nanowires and mesoporous carbon (CMK-3) nanorods, an Al metal anode and chloroaluminate ionic liquid electrolyte. The working mechanism of the Al-Se ...[more]

PMID: 29997871

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