Rechargeable aluminum batteries: effects of cations in ionic liquid electrolytes.

ABSTRACT: Room temperature ionic liquids (RTILs) are solvent-free liquids comprised of densely packed cations and anions. The low vapor pressure and low flammability make ILs interesting for electrolytes in batteries. In this work, a new class of ionic liquids were formed for rechargeable aluminum/graphite battery electrolytes by mixing 1-methyl-1-propylpyrrolidinium chloride (Py13Cl) with various ratios of aluminum chloride (AlCl₃) (AlCl₃/Py13Cl molar ratio = 1.4 to 1.7). Fundamental properties of the ionic liquids, including density, viscosity, conductivity, anion concentrations and electrolyte ion percent were investigated and compared with the previously investigated 1-ethyl-3-methylimidazolium chloride (EMIC-AlCl₃) ionic liquids. The results showed that the Py13Cl-AlCl₃ ionic liquid exhibited lower density, higher viscosity and lower conductivity than its EMIC-AlCl₃ counterpart. We devised a Raman scattering spectroscopy method probing ILs over a Si substrate, and by using the Si Raman scattering peak for normalization, we quantified speciation including AlCl₄ ^-, Al₂Cl₇ ^-, and larger AlCl₃ related species with the general formula (AlCl₃) _n in different IL electrolytes. We found that larger (AlCl₃) _n species existed only in the Py13Cl-AlCl₃ system. We propose that the larger cationic size of Py13⁺ (142 ų) versus EMI⁺ (118 ų) dictated the differences in the chemical and physical properties of the two ionic liquids. Both ionic liquids were used as electrolytes for aluminum-graphite batteries, with the performances of batteries compared. The chloroaluminate anion-graphite charging capacity and cycling stability of the two batteries were similar. The Py13Cl-AlCl₃ based battery showed a slightly larger overpotential than EMIC-AlCl₃, leading to lower energy efficiency resulting from higher viscosity and lower conductivity. The results here provide fundamental insights into ionic liquid electrolyte design for optimal battery performance.

SUBMITTER: Zhu G 

PROVIDER: S-EPMC9062991 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature