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A three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds.

ABSTRACT: The aromatic nucleophilic substitution reaction based synthesis of a three-armed cryptand displaying 2,4,6-triphenyl-1,3,5-triazine units as caps and pyridine rings in the bridges, along with NMR, MS and molecular modelling-based structural analysis of this compound are reported. Appropriate NMR and molecular modelling investigations proved the formation of 1:1 host-guest assemblies between the investigated cryptand and some polynuclear aromatic hydrocarbons or their derivatives.

SUBMITTER: Lar C

PROVIDER: S-EPMC6009098 | biostudies-literature | 2018

REPOSITORIES: biostudies-literature

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A three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds.

Lar Claudia C Woiczechowski-Pop Adrian A Bende Attila A Grosu Ioana Georgeta IG Miklášová Natalia N Bogdan Elena E Hădade Niculina Daniela ND Terec Anamaria A Grosu Ion I

Beilstein journal of organic chemistry 20180606

The aromatic nucleophilic substitution reaction based synthesis of a three-armed cryptand displaying 2,4,6-triphenyl-1,3,5-triazine units as caps and pyridine rings in the bridges, along with NMR, MS and molecular modelling-based structural analysis of this compound are reported. Appropriate NMR and molecular modelling investigations proved the formation of 1:1 host-guest assemblies between the investigated cryptand and some polynuclear aromatic hydrocarbons or their derivatives. ...[more]

PMID: 29977401

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