Ontology highlight
ABSTRACT:
SUBMITTER: Kiyokawa K
PROVIDER: S-EPMC6009488 | biostudies-literature | 2018
REPOSITORIES: biostudies-literature
Beilstein journal of organic chemistry 20180515
The decarboxylative acetoxylation of carboxylic acids using a combination of PhI(OAc)<sub>2</sub> and I<sub>2</sub> in a CH<sub>2</sub>Cl<sub>2</sub>/AcOH mixed solvent is reported. The reaction was successfully applied to two types of carboxylic acids containing an α-quaternary and a benzylic carbon center under mild reaction conditions. The resulting acetates were readily converted into the corresponding alcohols by hydrolysis. ...[more]