Unknown

Dataset Information

0

Hypervalent iodine(III)-induced methylene acetoxylation of 3-oxo-N-substituted butanamides.

ABSTRACT: 1-Carbamoyl-2-oxopropyl acetate derivatives were synthesized through an acetoxylation process to methylene with the aid of (diacetoxyiodo)benzene (DIB) as the oxidant. Not only mild reaction conditions, but also excellent yields and good substrate scope make the present protocol potentially useful in organic synthesis.

SUBMITTER: Liu WB 

PROVIDER: S-EPMC3205772 | biostudies-literature | 2011

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Hypervalent iodine(III)-induced methylene acetoxylation of 3-oxo-N-substituted butanamides.

Liu Wei-Bing WB   Chen Cui C   Zhang Qing Q   Zhu Zhi-Bo ZB  

Beilstein journal of organic chemistry 20111019

1-Carbamoyl-2-oxopropyl acetate derivatives were synthesized through an acetoxylation process to methylene with the aid of (diacetoxyiodo)benzene (DIB) as the oxidant. Not only mild reaction conditions, but also excellent yields and good substrate scope make the present protocol potentially useful in organic synthesis. ...[more]

Similar Datasets

Unknown Hypervalent Iodine(III)-Catalysed Enantioselective ?-Acetoxylation of Ketones.
| S-EPMC7496773 | biostudies-literature
Unknown Hypervalent iodine(III)-mediated decarboxylative acetoxylation at tertiary and benzylic carbon centers.
| S-EPMC6009488 | biostudies-literature
Unknown Hypervalent Iodine-Mediated Diastereoselective ?-Acetoxylation of Cyclic Ketones.
| S-EPMC7365914 | biostudies-literature
Unknown Hypervalent Iodine(III) Compounds as Biaxial Halogen Bond Donors.
| S-EPMC7252947 | biostudies-literature
Unknown Hypervalent Iodine(III)-Induced Domino Oxidative Cyclization for the Synthesis of Cyclopenta[b]furans.
| S-EPMC6274509 | biostudies-literature
Unknown Stereoselective Formation of Substituted 1,3-Dioxolanes through a Three-Component Assembly during the Oxidation of Alkenes with Hypervalent Iodine(III).
| S-EPMC6332268 | biostudies-literature
Unknown Enantioselective dioxytosylation of styrenes using lactate-based chiral hypervalent iodine(III).
| S-EPMC5870148 | biostudies-literature
Unknown A Benziodoxole-Based Hypervalent Iodine(III) Compound Functioning as a Peptide Coupling Reagent.
| S-EPMC7093377 | biostudies-literature
Unknown Hypervalent Iodine(III)-Promoted C3-H Regioselective Halogenation of 4-Quinolones under Mild Conditions.
| S-EPMC8675166 | biostudies-literature
Unknown Perfluoroalkylation of Aryl-N,N-dimethyl Hydrazones Using Hypervalent Iodine(III) Reagents or Perfluoroalkyl Iodides.
| S-EPMC5698881 | biostudies-literature